Electron paramagnetic resonance spectroscopy of Cr3+ in hexagonal Cs2NaGaF6 crystals

被引：0
|
作者：
Vrielinck, H
Khaidukov, NM
Callens, F
Matthys, P
机构：
[1] Univ Ghent, Dept Solid State Sci, B-9000 Ghent, Belgium
[2] Russian Acad Sci, Inst Gen & Inorgan Chem, Moscow 117907, Russia
来源：
RADIATION EFFECTS AND DEFECTS IN SOLIDS | 2002年 / 157卷 / 6-12期
关键词：
laser materials; fluoride crystals; transition metal ion; EPR;
D O I：
10.1080/10420150215764
中图分类号：
TL [原子能技术]; O571 [原子核物理学];
学科分类号：
0827 ; 082701 ;
摘要：
Powder samples of hydrothermally grown Cr3+ -doped Cs-2 NaGaF6 crystals have been investigated with electron paramagnetic resonance spectroscopy at X - (9.5 GHz) and Q -band (34 GHz). Analysis of the spectra clearly demonstrates that there are two distinct Cr3+ centres in the Cs2NaGaF6 crystal, having nearly identical g factors, but differing largely from the viewpoint of their zero field splitting. By using the Cr-53 hyperfine spectra observed with electron nuclear double resonance spectroscopy, it is deduced that these centres have opposite signs for the zero field splitting. The spectroscopic properties of the Cr3+ centres in the isostructural Cs2NaGaF6 and Cs2NaAlF6 crystals are compared and discussed.
引用
收藏
页码：1155 / 1159
页数：5
相关论文
共 50 条
  • [1] Investigation of Cr3+ ions in Cs2NaGaF6 single crystals by optical spectroscopy
    da Fonseca, RJM
    Tavares, AD
    Silva, PS
    Abritta, T
    Khaidukov, NM
    SOLID STATE COMMUNICATIONS, 1999, 110 (09) : 519 - 524
  • [2] Structure determination and a vibrational study for the hexagonal elpasolite Cs2NaGaF6:Cr3+
    Bordallo, HN
    Wang, X
    Hanif, KM
    Strouse, GF
    da Fonseca, RJM
    Sosman, LP
    Tavares, AD
    JOURNAL OF PHYSICS-CONDENSED MATTER, 2002, 14 (47) : 12383 - 12389
  • [3] Identification of Cr3+ centers in Cs2NaAlF6 and Cs2NaGaF6 crystals by EPR and ENDOR paramagnetic resonance techniques -: art. no. 144111
    Vrielinck, H
    Loncke, F
    Callens, F
    Matthys, P
    Khaidukov, NM
    PHYSICAL REVIEW B, 2004, 70 (14) : 144111 - 1
  • [4] Vibrational Analysis of the Elpasolites Cs2NaAlF6 and Cs2NaGaF6 Doped with Cr3+ Ions by Fluorescence Spectroscopy
    R. J. M. da Fonseca
    L. P. Sosman
    A. Dias Tavares
    H. N. Bordallo
    Journal of Fluorescence, 2000, 10 : 375 - 381
  • [5] Vibrational analysis of the elpasolites Cs2NaAlF6 and Cs2NaGaF6 doped with Cr3+ ions by fluorescence spectroscopy
    da Fonseca, RJM
    Sosman, LP
    Tavares, AD
    Bordallo, HN
    JOURNAL OF FLUORESCENCE, 2000, 10 (04) : 375 - 381
  • [6] Investigations of the optical band positions and spin-Hamiltonian parameters for two trigonal Cr3+ centers in Cs2NaGaF6: Cr3+ crystals
    Zhang, Xin-Xin
    Mei, Yang
    Liu, Gang
    Zheng, Wen-Chen
    OPTIK, 2016, 127 (18): : 7128 - 7131
  • [7] Investigation of optical spectra and local structure for (CrF6)3- cluster in Cs2NaAlF6:Cr3+ and Cs2NaGaF6:Cr3+ systems
    Huang Jin-Ling
    Kuang Xiao-Yu
    Li Ying
    CHEMICAL PHYSICS LETTERS, 2008, 458 (1-3) : 227 - 230
  • [8] Analysis of zero-field splitting (ZFS) and local distortion of Cr3+ ions doped into fluoroelpasolite (Cs2NaGaF6 and Cs2NaAlF6) crystals
    Acikgoz, Muhammed
    JOURNAL OF FLUORINE CHEMISTRY, 2013, 156 : 224 - 229
  • [9] Analysis of paramagnetic 3d ions (Cr3+ and Fe3+) centers in fluoroelpasolite Cs2NaGaF6 crystal by both DFT and SPM calculations
    Erbahar, D.
    Emul, Y.
    Acikgoz, M.
    CHEMICAL PHYSICS, 2018, 501 : 93 - 100
  • [10] Optical properties of Mn3+ ions in Cs2NaAlF6 and Cs2NaGaF6 single crystals
    da Fonseca, R. J. M.
    Sosman, L. P.
    Camara, A. R.
    OPTICAL MATERIALS, 2017, 64 : 323 - 326
12345