Cadmium Metal-Directed Three-Dimensional Coordination Polymers: In Situ Tetrazole Ligand Synthesis, Structures, and Luminescent Properties

被引:99
|
作者
Qiu, Yongcai [1 ,2 ,3 ,4 ]
Li, Yinghua [1 ,2 ,3 ]
Peng, Guo [1 ,2 ,3 ]
Cai, Jinbiao [1 ,2 ,3 ]
Jin, Limin [1 ,2 ,3 ]
Ma, Li [1 ,2 ,3 ]
Deng, Hong [1 ,2 ,3 ]
Zeller, Matthias [5 ]
Batten, Stuart R. [6 ]
机构
[1] S China Normal Univ, Sch Chem & Environm, Guangzhou 510006, Guangdong, Peoples R China
[2] S China Normal Univ, Key Lab Electrochem Technol Energy Storage, Guangzhou 510006, Guangdong, Peoples R China
[3] S China Normal Univ, Power Generat Guangdong Univ, Guangzhou 510006, Guangdong, Peoples R China
[4] Hong Kong Univ Sci & Technol, Dept Chem, Nano Sci & Technol Program, Kowloon, Hong Kong, Peoples R China
[5] Youngstown State Univ, Dept Chem, Youngstown, OH 44555 USA
[6] Monash Univ, Sch Chem, Clayton, Vic 3800, Australia
基金
中国国家自然科学基金;
关键词
SECONDARY BUILDING UNITS; ORGANIC FRAMEWORK; CRYSTAL-STRUCTURES; SUPRAMOLECULAR ARCHITECTURES; HYDROTHERMAL SYNTHESES; POROUS MATERIALS; RATIONAL DESIGN; COMPLEXES; CHEMISTRY; CARBOXYLATES;
D O I
10.1021/cg9013619
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Seven three-dimensional (3D) cadmium coordination frameworks, {[Cd(5MT)(2)] (1a); [Cd-5(N-3)(5MT)(9)center dot 0.12H(2)O] (1b); [Cd-3(OH)Cl-1.39(N-3)(0.61)(5MT)(3)] (1c), 5MT = 5-methyl-tetrazole}; {[Cd-3(OH)Cl(N-3)(5AT)(3) (2a); Cd-2(OH)Br(5AT)(2) (2b), 5AT = 5-amino-tetrazole]}; {[Cd7Cl2(5BT)(12)(H2O)(2) (3a); and [Cd7Br2(5BT)(12)(H2O)(2) (3b), 5BT = 5-butyltetrazole], were obtained through in situ tetrazole synthesis and have been structurally characterized by elemental analyses, Fourier transform infrared spectroscopy, thermal studies. and single crystal and powder X-ray diffraction. Compounds la and 1b were constructed by the interconnection of 5MT and cadmium metal ions, kind both exhibited distinct topological nets: la has a diamond-like framework, while 1b has the acs topological net. Compounds le and 2a represented similar structural network motifs; both were intricate coordination polymers constructed from interconnected {ClCd3O} subnets through tetrazole anions. Compound 2b was constructed From two-dimensional (2D) wavelike {BrCd3O} layers bridged by 5AT anions. Compounds 3a and 3b were structural isomorphs, constructed from 2D Cd-5BT wheel layers and halogen linkers. Furthermore, the luminescent properties of these complexes were investigated.
引用
收藏
页码:1332 / 1340
页数:9
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