Synthesis of amines via coupling of imines and alkylarenes

被引：2
|
作者：
Nair, Vaishnavi N. [1 ]
Tambar, Uttam K. [1 ]
机构：
[1] Univ Texas Southwestern Med Ctr, Dept Biochem, 5323 Harry Hines Blvd, Dallas, TX 75390 USA
来源：
TETRAHEDRON LETTERS | 2022年 / 98卷
基金：
美国国家卫生研究院;
关键词：
C-H functionalization; Amine; Imine; Radical; Alkylarene; Photochemistry; C-H BONDS; C(SP(3))-H FUNCTIONALIZATION; TRANSFER HYDROGENATION; HYDROAMINATION; PHOTOREDOX; ACTIVATION; ACIDITIES;
D O I：
10.1016/j.tetlet.2022.153788
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
Recent advances in selective C-H functionalization have resulted in powerful strategies for the synthesis of important target molecules from petroleum-derived hydrocarbons. In particular, alkylarenes such as toluene and xylenes are abundant feedstock chemicals that are emerging as useful substrates in C-C and C-X bond forming reactions. We review benzylic C-H functionalization of alkylarenes for the synthesis of amines. We focus on the direct coupling of alkylarenes and imines through two distinct modes of activation: heterolytic and homolytic cleavage of benzylic C-H bonds.(c) 2022 Elsevier Ltd. All rights reserved.
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页数：8
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