Aggregation of fullerene C60 in N-methylpyrrolidone and N-methylmorpholine

被引:0
|
作者
Evlampieva, NP
Polushin, SG
Lavrenko, PN
Korneeva, EV
Zgonnik, VN
Ryumtsev, EI
机构
[1] St Petersburg State Univ, Inst Phys Res, St Petersburg 199164, Russia
[2] Russian Acad Sci, Inst Macromol Cpds, St Petersburg 199004, Russia
来源
RUSSIAN JOURNAL OF PHYSICAL CHEMISTRY | 2000年 / 74卷 / 07期
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中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
Using translational diffusion, viscosimetry, and Kerr electrooptical techniques, it was found that the properties of fullerene C-60 in the N-methylpyrrolidone and N-methylmorpholine media are determined by the duration of storage of the solutions. It was shown that, in these solvents, the fullerene passes into solution in the form of individual molecules, forming fullerene-solvent aggregates. The physical properties of these aggregates (the degree of asymmetry and optical anisotropy) were found to vary with time.
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页码:1183 / 1187
页数:5
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