Structural Effects on the Oxygen Reduction Reaction on Pt Single-Crystal Electrodes Modified with Melamine

被引:23
|
作者
Wada, Naoya [1 ]
Nakamura, Masashi [1 ]
Hoshi, Nagahiro [1 ]
机构
[1] Chiba Univ, Dept Appl Chem & Biotechnol, Grad Sch Engn, Inage Ku, 1-33 Yayoi Cho, Chiba 2638522, Japan
关键词
Enhancement of oxygen reduction reaction; High-index planes of Pt; Melamine; Hydrophobic species; ROTATING-DISK HMRD; ELECTROCATALYTIC ACTIVITY; PLATINUM NANOPARTICLES; SURFACES; ENHANCEMENT; PT(111);
D O I
10.1007/s12678-020-00584-0
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
Structural effects on the oxygen reduction reaction (ORR) on Pt single-crystal electrodes modified with melamine have been investigated. The activity of ORR on Pt(111) modified with melamine was threefold that on bare Pt(111). The ORR activity of Pt(331) = 3(111)-(111), which was the highest among the Pt single-crystal electrodes studied, was increased twofold after the modification with melamine. The ORR activities of other high-index planes (n(111)-(111) series) were also increased after electrode modification with melamine. Graphical
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页码:275 / 281
页数:7
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