Synthesis and characterization of novel triphenylene derivatives having carboxylic acid groups at the peripheral chains

被引:0
|
作者
Li, Zhongxiao [1 ]
Wei, Wei [1 ]
Fan, Wukun [1 ]
Pu, Jialing [1 ]
机构
[1] Beijing Inst Graph Commun, Lab Printing & Packing Mat & Technol, Beijing Key Lab, Beijing 102600, Peoples R China
来源
ADVANCES IN LIQUID CRYSTALS | 2010年 / 428-429卷
关键词
Triphenylene; Carboxylic acid; Hydrogen bond; LIQUID-CRYSTALLINE IONOMERS; DISCOTICS; ORIENTATION;
D O I
10.4028/www.scientific.net/KEM.428-429.83
中图分类号
O7 [晶体学];
学科分类号
0702 ; 070205 ; 0703 ; 080501 ;
摘要
A new kind of triphenylene derivative sym-(OC3H6OCOC2H4COOH)(6) with triphenylene at the core and carboxyl groups at the peripheral chains was synthesized and characterized by FT-IR and H-1-NMR. Thermal gravimetry analysis (TGA) and differential scanning calorimetry (DSC) showed that these compounds have a good thermal stability, which is dependent on the flexibility and interaction of the peripheral chains. Red shifts in electronic absorption spectra of the compounds were found in solution with increasing concentration.
引用
收藏
页码:83 / 89
页数:7
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