Effect of heating rate on nanoparticle formation of poly(N-isopropylacrylamide)-poly(ethylene glycol) block copolymer microgels

被引:46
|
作者
Zhu, PW [1 ]
Napper, DH [1 ]
机构
[1] Univ Sydney, Sch Chem, Sydney, NSW 2006, Australia
关键词
D O I
10.1021/la000489+
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
The colloidal behavior of poly(N-isopropylacrylamide) and poly(ethylene oxide) (PNIPAM-b-PEO) block copolymers and their corresponding microgels in aqueous solutions were studied. The microgels were synthesized using a redox system consisting of ceric ion (Ce) and PEO. The nanoparticles formation of the microgels were controlled by changing the heating rates. Smaller particle dimension with a narrower size microgels were obtained by the fast heating process.
引用
收藏
页码:8543 / 8545
页数:3
相关论文
共 50 条
  • [1] Aggregation of block copolymer microgels of poly-(N-isopropylacrylamide) and poly(ethylene glycol)
    Zhu, PW
    Napper, DH
    MACROMOLECULES, 1999, 32 (06) : 2068 - 2070
  • [2] Thermogelation properties of poly(N-isopropylacrylamide) - block - poly(ethylene glycol) - block - poly(N-isopropylacrylamide) triblock copolymer aqueous solutions
    Teodorescu, Mircea
    Negru, Ioana
    Stanescu, Paul O.
    Draghici, Constantin
    Lungu, Anamaria
    Sarbu, Andrei
    REACTIVE & FUNCTIONAL POLYMERS, 2010, 70 (10): : 790 - 797
  • [3] The Effect of Hydrophilic Bentonite Nanoclay on the Thermogelation Properties of Poly(N-isopropylacrylamide)-poly(ethylene glycol)-poly(N-isopropylacrylamide) Triblock Copolymer Aqueous Solutions
    Ioan, Livia
    Teodorescu, Mircea
    Stanescu, Paul O.
    Draghici, Constantin
    Zaharia, Anamaria
    Sarbu, Andrei
    Stoleriu, Stefania
    JOURNAL OF MACROMOLECULAR SCIENCE PART B-PHYSICS, 2015, 54 (03): : 316 - 328
  • [4] From poly(N-isopropylacrylamide)-block-poly(ethylene oxide)-block-poly(N-isopropylacrylamide) triblock copolymer to poly(N-isopropylacrylamide)-block-poly(ethylene oxide) hydrogels: Synthesis and rapid deswelling and reswelling behavior of hydrogels
    Zheng, Qinqin
    Zheng, Sixun
    JOURNAL OF POLYMER SCIENCE PART A-POLYMER CHEMISTRY, 2012, 50 (09) : 1717 - 1727
  • [5] pH and thermo-responsive poly(N-isopropylacrylamide) copolymer grafted to poly(ethylene glycol)
    Abdullah-Al-Nahain
    Lee, Kang Seok
    Mosaiab, Tamim
    Park, Sung Young
    JOURNAL OF APPLIED POLYMER SCIENCE, 2013, 130 (01) : 168 - 174
  • [6] Surface-grafted block copolymer brushes with continuous composition gradients of poly(poly(ethylene glycol)-monomethacrylate) and poly(N-isopropylacrylamide)
    LI LinHui
    Department of Polymer Science and Engineering
    Science China Chemistry, 2011, (02) : 334 - 342
  • [7] Surface-grafted block copolymer brushes with continuous composition gradients of poly(poly(ethylene glycol)-monomethacrylate) and poly(N-isopropylacrylamide)
    LinHui Li
    JinDan Wu
    ChangYou Gao
    Science China Chemistry, 2011, 54 : 334 - 342
  • [8] Surface-grafted block copolymer brushes with continuous composition gradients of poly(poly(ethylene glycol)-monomethacrylate) and poly(N-isopropylacrylamide)
    Li LinHui
    Wu JinDan
    Gao ChangYou
    SCIENCE CHINA-CHEMISTRY, 2011, 54 (02) : 334 - 342
  • [9] Surface-grafted block copolymer brushes with continuous composition gradients of poly(poly(ethylene glycol)-monomethacrylate) and poly(N-isopropylacrylamide)
    LI LinHui WU JinDan GAO ChangYou MOE Key Laboratory of Macromolecular Synthesis and Functionalization
    Department of Polymer Science and Engineering Zhejiang University Hangzhou China
    Science China(Chemistry), 2011, 54 (02) : 334 - 342
  • [10] Influence of preparation conditions of poly (ethylene glycol)/poly (N-isopropylacrylamide) block copolymers on their properties
    Shimizu, H
    Yokohara, T
    Wada, R
    Okabe, M
    KOBUNSHI RONBUNSHU, 2004, 61 (12) : 640 - 642