Highly CO Selective Trimetallic Metal-Organic Framework Electrocatalyst for the Electrochemical Reduction of CO2

被引:7
|
作者
Phuc, Tran-Van [1 ]
Chung, Jin-Suk [1 ]
Hur, Seung-Hyun [1 ]
机构
[1] Univ Ulsan, Sch Chem Engn, Daehak Ro 93, Ulsan 44610, South Korea
基金
新加坡国家研究基金会;
关键词
metal-organic framework; electrocatalyst; electrochemical reduction of CO2; CO selectivity; stability; CARBON-DIOXIDE; CU; NANOPARTICLES; OXIDATION; PD; ELECTROREDUCTION; CATALYSIS; XPS;
D O I
10.3390/catal11050537
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
Pd, Cu, and Zn trimetallic metal-organic framework electrocatalysts (PCZs) based on benzene-1,3,5-tricarboxylic were synthesized using a simple solvothermal synthesis. The as-synthesized PCZ catalysts exhibited as much as 95% faradaic efficiency towards CO, with a high current density, low onset potential, and excellent long-term stability during the electrocatalytic reduction of CO2.
引用
收藏
页数:11
相关论文
共 50 条
  • [1] Highly selective metal-organic framework-based electrocatalyst for the electrochemical reduction of CO2 to CO
    Tran Van Phuc
    Kang, Sung Gu
    Chung, Jin Suk
    Hur, Seung Hyun
    [J]. MATERIALS RESEARCH BULLETIN, 2021, 138
  • [2] Highly CO selective Ca and Zn hybrid metal-organic framework electrocatalyst for the electrochemical reduction of CO2
    Tran Van Phuc
    Kang, Sung Gu
    Chung, Jin Suk
    Hur, Seung Hyun
    [J]. CURRENT APPLIED PHYSICS, 2021, 27 : 31 - 37
  • [3] Metal-organic framework composites for electrochemical CO2 reduction reaction
    Adegoke, Kayode A.
    Ighalo, Joshua O.
    Conradie, Jeanet
    Ohoro, Chinemerem R.
    Amaku, James F.
    Oyedotun, Kabir O.
    Maxakato, Nobanathi W.
    Akpomie, Kovo G.
    Okeke, Emmanuel Sunday
    Olisah, Chijioke
    Malloum, Alhadji
    [J]. SEPARATION AND PURIFICATION TECHNOLOGY, 2024, 341
  • [4] A bifunctional catalyst derived from copper metal-organic framework for highly selective photocatalytic CO2 reduction and CO2 cycloaddition reaction
    Xie, Xiaoying
    Li, Haoyun
    Cao, Weiwei
    Ke, Da
    Dong, Zhuo
    Tian, Li
    Xiong, Xuyang
    Zhang, Jingbo
    [J]. JOURNAL OF MOLECULAR STRUCTURE, 2024, 1312
  • [5] Ultra-thin Two-Dimensional Trimetallic Metal-Organic Framework for Photocatalytic Reduction of CO2
    Hu, Mingliang
    Liu, Jiahao
    Song, Shaojia
    Wang, Weiwei
    Yao, Jiasai
    Gong, Yixuan
    Li, Chenyu
    Li, Huan
    Li, Yanjie
    Yuan, Xilin
    Fang, Zhao
    Xu, Hao
    Song, Weiyu
    Li, Zhenxing
    [J]. ACS CATALYSIS, 2022, 12 (05) : 3238 - 3248
  • [6] Electrochemical Reduction of CO2 to CO by a Heterogeneous Catalyst of Fe-Porphyrin-Based Metal-Organic Framework
    Dong, Bao-Xia
    Qian, She-Liang
    Bu, Fan-Yan
    Wu, Yi-Chen
    Feng, Li-Gang
    Teng, Yun-Lei
    Liu, Wen-Long
    Li, Zong-Wei
    [J]. ACS APPLIED ENERGY MATERIALS, 2018, 1 (09): : 4662 - 4669
  • [7] Synthesis of heterometallic metal-organic frameworks and their performance as electrocatalyst for CO2 reduction
    Perfecto-Irigaray, Maite
    Albo, Jonathan
    Beobide, Garikoitz
    Castillo, Oscar
    Irabien, Angel
    Perez-Yanez, Sonia
    [J]. RSC ADVANCES, 2018, 8 (38) : 21092 - 21099
  • [8] A Highly Selective Copper-Indium Bimetallic Electrocatalyst for the Electrochemical Reduction of Aqueous CO2 to CO
    Rasul, Shahid
    Anjum, Dalaver H.
    Jedidi, Abdesslem
    Minenkov, Yury
    Cavallo, Luigi
    Takanabe, Kazuhiro
    [J]. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2015, 54 (07) : 2146 - 2150
  • [9] Phase-enabled metal-organic framework homojunction for highly selective CO2 photoreduction
    Yannan Liu
    Chuanshuang Chen
    Jesus Valdez
    Debora Motta Meira
    Wanting He
    Yong Wang
    Catalin Harnagea
    Qiongqiong Lu
    Tugrul Guner
    Hao Wang
    Cheng-Hao Liu
    Qingzhe Zhang
    Shengyun Huang
    Aycan Yurtsever
    Mohamed Chaker
    Dongling Ma
    [J]. Nature Communications, 12
  • [10] Electrochemical conversion of CO2 using metal-organic framework catalysts
    Andres Espinosa-Flores, Rodrigo
    Daniel Trejo-Valdez, Martin
    Elena Manriquez-Ramirez, Maria
    Javier Tzompantzi-Morales, Francisco
    [J]. HELIYON, 2023, 9 (06)