Ruthenium(II) complexes containing triphenylphosphine/triphenylarsine and bidentate Schiff bases derived from 2-hydroxy-1-naphthaldehyde and primary amines

被引：10
|
作者：
Balasubramanian, KP
Chinnusamy, V
Karvembu, R
Natarajan, K [1 ]
机构：
[1] Bharathiar Univ, Dept Chem, Coimbatore 641046, Tamil Nadu, India
[2] Sri Ramakrishna Mission Vidyalaya Coll Arts & Sci, Dept Chem, Coimbatore 641020, Tamil Nadu, India
来源：
TRANSITION METAL CHEMISTRY | 2004年 / 29卷 / 06期
关键词：
D O I：
10.1007/s11243-004-4993-8
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
The synthesis and characterisation of some new hexa-coordinated Schiff base complexes of the type [RuCl(CO)(EPh3)(B)(L)] (E = P or As; B = PPh3 or AsPh3 or py or pip; L = anion of the Schiff bases derived from 2-hydroxy-1-naphthaldehyde and aniline, 4-chloroaniline or 2-methylaniline) are reported. I.r., electronic, H-1-n.m.r, P-31-n.m.r. spectra, catalytic activity and antibacterial activity of the complexes are discussed. An octahedral structure has been tentatively proposed for all the complexes.
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页码：644 / 648
页数：5
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