Synthesis of a Novel Benzothiazole-Rhodamine Derivative and Its Selective Detection of Fe3+, Al3+ and Cr3+

被引:8
|
作者
Hou, Shuhua [1 ]
Qu, Zhonggu [1 ]
Zhong, Keli [1 ]
Bian, Yanjiang [1 ]
Tang, Lijun [1 ]
机构
[1] Bohai Univ, Dept Chem, Jinzhou 121013, Peoples R China
关键词
rhodamine; benzothiazole; click chemistry; FLUORESCENT-PROBES; SENSOR; CHEMOSENSOR; IONS; IRON; HG2+; RECOGNITION; INDICATORS; RECEPTOR; STATE;
D O I
10.6023/cjoc201512041
中图分类号
O62 [有机化学];
学科分类号
070303 ; 081704 ;
摘要
A novel rhodamine-based probe L was synthesized from rhodamine B through "click chemistry". It showed that probe L acted as a naked-eye and "turn on" fluorescent probe for Fe3+, Al3+ and Cr3+ recognition. L is highly selective to trivalent ions (Fe3+, Al3+ and Cr3+) over other monovalent or divalent ions in CH3OH. Detection limits of probe L for Fe3+, Cr3+ and Al3+ are 9.7 X 10(-5), 6.9 X 10(-5) and 1.4 X 10(-4) mol/L, respectively, which could make it potentially applicable in Fe3+, Cr3+ and Al3+ detection.
引用
收藏
页码:768 / 773
页数:6
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