Interactions and glass formation in the TlAs2Se4-Tl3As2Se3Te3 system

被引：2
|
作者：
Aliev, I. I. [1 ]
Aliev, I. G. [1 ]
机构：
[1] Natl Acad Sci Azerbaijan, Nagiev Inst Chem Problems, AZ-1143 Baku, Azerbaijan
来源：
RUSSIAN JOURNAL OF INORGANIC CHEMISTRY | 2010年 / 55卷 / 07期
关键词：
Glass Formation; Glassy Alloy; Microhard Ness; Title System; Chalco Genides;
D O I：
10.1134/S0036023610070260
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
The TlAs2Se4-Tl3As2Se3Te3 system was studied using differential thermal analysis (DTA), powder X-ray diffraction, microstructure observation, and microhardness and density measurements. A phase diagram of the title system was constructed. This system is a quasi-binary join of the TlSe-As2Se3-As2Te3 quasi-ternary system. All alloys of the system under standard conditions are prepared in the glassy form. The system has a eutectic, which contains 50 mol % Tl3As2Se3Te3 and melts at 150A degrees C. The TlAs2Se4-base solid solution in the system extends to 12 mol % Tl3As2Se3Te3, and Tl3As2Se3Te3-based solid solution extends to 20 mol % TlAs2Se4.
引用
收藏
页码：1142 / 1145
页数：4
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