Solvent-Free Lithium/Sodium-Based Metal-Organic Frameworks with Versatile Nitrogen-Rich Ligands: Insight for the Design of Promising Superheat-Resistant Explosives

被引：24

作者：

Liang, Chen ^{[1
]}

Yang, Jiahui ^{[1
]}

Guo, Yan ^{[1
]}

Yuan, Fei ^{[2
]}

Song, Weiming ^{[1
]}

Xi, Jing ^{[1
]}

Liu, Xiangyu ^{[1
]}

Chen, Sanping ^{[2
]}

机构：

[1] Ningxia Univ, Coll Chem & Chem Engn, Natl Demonstrat Ctr Expt Chem Educ, State Key Lab High Efficiency Utilizat Coal & Gre, Yinchuan 750021, Ningxia, Peoples R China

[2] Northwest Univ, Coll Chem & Mat Sci, Sch Chem Engn, Xian 710069, Shaanxi, Peoples R China

来源：

INORGANIC CHEMISTRY | 2021年 / 60卷 / 13期

关键词：

ENERGETIC PERFORMANCE;

D O I：

10.1021/acs.inorgchem.1c01658

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Energetic metal-organic frameworks (EMOFs) are very promising as heat-resistant explosives, affording both thermal stability and energy properties. In this work, the self-assembly of high-energy nitrogen-rich linkers with nontoxic alkali-metal lithium/sodium leads to four new solvent-free EMOFs. Because of unparalleled decomposition temperature (T-dec = 403 degrees C) and heats of detonation (3.475 kcal.g(-1)), a 3D Li(I)-EMOF can be considered to be a superheat-resistant explosive candidate.

引用

页码：9282 / 9286

页数：5

共 3 条

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[3] In situ interface engineering of highly nitrogen-rich triazine-based covalent organic frameworks for an ultra-stable, dendrite-free lithium-metal anode
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ENERGY & ENVIRONMENTAL SCIENCE, 2024, 17 (03) : 1117 - 1131

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