Improving the Efficiency of Mustard Gas Simulant Detoxification by Tuning the Singlet Oxygen Quantum Yield in Metal-Organic Frameworks and Their Corresponding Thin Films

被引：72
|
作者：
Buru, Cassandra T. [1 ]
Majewski, Marek B. [2 ,4 ]
Howarth, Ashlee J. [1 ,4 ]
Lavroff, Robert H. [1 ]
Kung, Chung-Wei [1 ]
Peters, Aaron W. [1 ]
Goswami, Subhadip [1 ]
Farha, Omar K. [1 ,3 ]
机构：
[1] Northwestern Univ, Dept Chem, 2145 Sheridan Rd, Evanston, IL 60208 USA
[2] Northwestern Univ, Argonne Northwestern Solar Energy Res ANSER Ctr, Evanston, IL 60208 USA
[3] King Abdulaziz Univ, Fac Sci, Dept Chem, Jeddah 21589, Saudi Arabia
[4] Concordia Univ, Dept Chem & Biochem, 7141 Sherbrooke St W, Montreal, PQ H4B 1R6, Canada
来源：
ACS APPLIED MATERIALS & INTERFACES | 2018年 / 10卷 / 28期
基金：
美国国家科学基金会;
关键词：
chemical warfare agents; metal-organic frameworks; photosensitizer; singlet oxygen quantum yield; thin films; CHEMICAL WARFARE AGENTS; SULFUR MUSTARD; SELECTIVE PHOTOOXIDATION; COORDINATION POLYMERS; OXIDATION; SULFIDES; ANALOGS; CHARGE; STATE; MOFS;
D O I：
10.1021/acsami.8b05792
中图分类号：
TB3 [工程材料学];
学科分类号：
0805 ; 080502 ;
摘要：
The photocatalytically driven partial oxidation of a mustard gas simulant, 2-chloroethyl ethyl sulfide (CEES), was studied using the perylene-based metalorganic framework (MOF) UMCM-313 and compared to the activities of the Zr-based MOFs: PCN-222/MOF-545 and NU-1000. The rates of CEES oxidation positively correlated with the singlet oxygen quantum yield of the MOF linkers, porphyrin (PCN-222/MOF-545) < pyrene (NU-1000) < perylene (UMCM-313). Subsequently, thin films of UMCM-313 and NU-1000 were solvothermally grown on a conductive glass substrate to minimize catalyst loading and prevent light scattering by suspended MOF particles. Using a conductive glass support, the initial turnover frequencies of the MOFs in the photocatalytic reaction improved by 10-fold.
引用
收藏
页码：23802 / 23806
页数：5
相关论文
共 12 条
  • [1] Detoxification of a Mustard-Gas Simulant by Nanosized Porphyrin-Based Metal-Organic Frameworks
    Pereira, Carla F.
    Liu, Yangyang
    Howarth, Ashlee
    Figueira, Flavio
    Rocha, Joao
    Hupp, Joseph T.
    Farha, Omar K.
    Tome, Joao P. C.
    Almeida Paz, Filipe A.
    ACS APPLIED NANO MATERIALS, 2019, 2 (01) : 465 - 469
  • [2] Metalloporphyrinic metal-organic frameworks for enhanced photocatalytic degradation of a mustard gas simulant
    Quon, Alisa S.
    Manriquez, Doroteo
    Nguyen, Anna
    Papazyan, Edgar K.
    Wijeratne, Pavithra
    An, Lun
    Qi, Long
    Tang, Matthew J.
    Ready, Austin D.
    Farha, Omar K.
    Liu, Yangyang
    CHEMICAL COMMUNICATIONS, 2024, 61 (01) : 77 - 80
  • [3] Determination of Singlet Oxygen Quantum Yield of a Porphyrinic Metal-Organic Framework
    Hao, Yajiao
    Liu, Brandon M.
    Bennett, Timothy F.
    Monsour, Charlotte G.
    Selke, Matthias
    Liu, Yangyang
    JOURNAL OF PHYSICAL CHEMISTRY C, 2021, 125 (13): : 7392 - 7400
  • [4] Superoxide Ion and Singlet Oxygen Photogenerated by Metalloporphyrin-Based Metal-Organic Frameworks for Highly Efficient and Selective Photooxidation of a Sulfur Mustard Simulant
    Long, Zi-Hao
    Luo, Dong
    Wu, Kun
    Chen, Zi-Ye
    Wu, Ming-Min
    Zhou, Xiao-Ping
    Li, Dan
    ACS APPLIED MATERIALS & INTERFACES, 2021, 13 (31) : 37102 - 37110
  • [5] Enhancing the singlet oxygen capture and release rate of metal-organic frameworks through interpenetration tuning
    Jing Hao
    Feifan Lang
    Liqin Hao
    Yi Yang
    Lulu Zhang
    Hao Zhang
    Quan-Wen Li
    Jiandong Pang
    Xian-He Bu
    Chinese Chemical Letters, 2023, 34 (12) : 502 - 506
  • [6] Postsynthetic Incorporation of a Singlet Oxygen Photosensitizer in a Metal-Organic Framework for Fast and Selective Oxidative Detoxification of Sulfur Mustard
    Howarth, Ashlee J.
    Buru, Cassandra T.
    Liu, Yangyang
    Ploskonka, Ann M.
    Hartlieb, Karel J.
    McEntee, Monica
    Mahle, John J.
    Buchanan, James H.
    Durke, Erin M.
    Al-Juaid, Salih S.
    Stoddart, J. Fraser
    DeCoste, Jared B.
    Hupp, Joseph T.
    Farha, Omar K.
    CHEMISTRY-A EUROPEAN JOURNAL, 2017, 23 (01) : 214 - 218
  • [7] Two Polymorphic Polyoxometalate-Based Metal-Organic Frameworks for the Efficient Synthesis of Functionalized Sulfoxides and Detoxification of Mustard Gas Simulants
    Chen, Yanhong
    Chang, Shenzhen
    An, Haiyan
    Li, Yanqin
    Zhu, Qingshan
    Luo, Huiyun
    Huang, Yaohui
    ACS SUSTAINABLE CHEMISTRY & ENGINEERING, 2021, 9 (46) : 15683 - 15693
  • [8] Liquid- and Gas-Phase Diffusion of Ferrocene in Thin Films of Metal-Organic Frameworks
    Zhou, Wencai
    Woell, Christof
    Heinke, Lars
    MATERIALS, 2015, 8 (06) : 3767 - 3775
  • [9] One-pot synthesis of a porphyrin functionalized metal-organic frameworks as a recyclable visible-light-driven photosensitizer for efficient detoxification of a sulfur mustard simulant in air
    Zhou, Jinfeng
    Li, Xiangqian
    Chu, Chunjie
    Cao, Jinping
    MICROPOROUS AND MESOPOROUS MATERIALS, 2024, 375
  • [10] Hollow Lindqvist-like-Shaped {V6} Cluster-Based Metal-Organic Framework for the Highly Efficient Detoxification of Mustard Gas Simulant
    Tian, Hong-Rui
    Zhang, Zhong
    Dang, Tian-Yi
    Liu, Shu-Mei
    Lu, Ying
    Liu, Shu-Xia
    INORGANIC CHEMISTRY, 2021, 60 (02) : 841 - 846
12