The Role of Stress in the Self-Organized Growth of Porous Anodic Alumina

被引:15
|
作者
Liao, Jinfu [1 ]
Ling, Zhiyuan [1 ]
Li, Yi [1 ]
Hu, Xing [1 ]
机构
[1] S China Univ Technol, Dept Elect Mat Sci & Engn, Guangzhou 510640, Guangdong, Peoples R China
关键词
porous anodic alumina; barrier layer etching stress distribution; cell interaction; self-organization; VOLUME EXPANSION; BARRIER LAYER; INITIAL GROWTH; OXIDE; ACID; DISSOLUTION; FABRICATION; TRACER; GENERATION; MEMBRANES;
D O I
10.1021/acsami.6b00703
中图分类号
TB3 [工程材料学];
学科分类号
0805 ; 080502 ;
摘要
Ridges and depressions were formed on the barrier layer during chemical and physical etching of porous anodic alumina (PAA) from the bottom side, indicating nonuniform etching rate around each cell. These behaviors cannot be explained solely by the well-known composition variation, but were in line with the hexagonal distribution of stress within the barrier layer of each cell. Such stress variation should be attributed to the interactions of neighboring cells undergoing volume expansion. These interactions could account for the self-organization of PAA.
引用
收藏
页码:8017 / 8023
页数:7
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