Hydrolytic synthesis and structural characterization of five hexanuclear oxo-hydroxo lanthanide clusters

被引：23
|
作者：
Tong, Yu-Zhang [1 ]
Wang, Qing-Lun [1 ]
Yang, Guang [1 ]
Yang, Guang-Ming [1 ]
Yan, Shi-Ping [1 ]
Liao, Dai-Zheng [2 ]
Cheng, Peng [1 ]
机构：
[1] Nankai Univ, Dept Chem, Tianjin 300071, Peoples R China
[2] Nankai Univ, Key Lab Met & Mol Mat Chem Tianjin City, Tianjin 300071, Peoples R China
来源：
CRYSTENGCOMM | 2010年 / 12卷 / 02期
基金：
中国国家自然科学基金;
关键词：
EARTH BASIC NITRATES; CRYSTAL-STRUCTURES; COMPLEXES; GD; TB; LN; CHEMISTRY; CATALYSIS; IODIDE; EU;
D O I：
10.1039/b914208h
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Five hexanuclear oxo-hydroxo lanthanide clusters are synthesized by hydrolysis of the lanthanide ions together with 4-amido-3,5-dimethyl-1,2,4-triazole (L). They all have a [Ln(6)(mu(6)-O)(mu(3)-OH)(8)](8+) core structure and the triazole groups stabilize the core structure in different fashions. The oxo group functions as an anion template to induce the self-assembly of lanthanide ions.
引用
收藏
页码：543 / 548
页数：6
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