Saddles and dynamics in a solvable mean-field model

被引:7
|
作者
Angelani, L
Ruocco, G
Zamponi, F
机构
[1] Univ Roma La Sapienza, Dipartimento Fis, INFM, I-00185 Rome, Italy
[2] Univ Roma La Sapienza, SMC, INFM, I-00185 Rome, Italy
来源
JOURNAL OF CHEMICAL PHYSICS | 2003年 / 118卷 / 18期
关键词
D O I
10.1063/1.1565996
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
We use the saddle-approach, recently introduced in the numerical investigation of simple model liquids, in the analysis of a mean-field solvable system. The investigated system is the k-trigonometric model, a k-body interaction mean field system, that generalizes the trigonometric model introduced by Madan and Keyes [J. Chem. Phys. 98, 3342 (1993)] and that has been recently introduced to investigate the relationship between thermodynamics and topology of the configuration space. We find a close relationship between the properties of saddles (stationary points of the potential energy surface) visited by the system and the dynamics. In particular the temperature dependence of saddle order follows that of the diffusivity, both having an Arrhenius behavior at low temperature and a similar shape in the whole temperature range. Our results confirm the general usefulness of the saddle-approach in the interpretation of dynamical processes taking place in interacting systems. (C) 2003 American Institute of Physics.
引用
收藏
页码:8301 / 8306
页数:6
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