A new tris(ferrocenylamine) ditertiary phosphine: Synthesis and co-ordination studies

被引:5
|
作者
Elsegood, Mark R. J. [1 ]
Lake, Andrew J. [1 ]
Mortimer, Roger J. [1 ]
Smith, Martin B. [1 ]
Weaver, George W. [1 ]
机构
[1] Univ Loughborough, Dept Chem, Loughborough LE11 3TU, Leics, England
基金
英国工程与自然科学研究理事会;
关键词
Phosphine ligands; Ferrocenyl compounds; Organometallic complexes; X-ray crystallography; Electrochemical studies; PALLADIUM(II) COMPLEXES; RUTHENIUM COMPLEXES; LIGANDS; CHEMISTRY; ELECTROCHEMISTRY; RECEPTORS;
D O I
10.1016/j.jorganchem.2010.04.012
中图分类号
O61 [无机化学];
学科分类号
070301 ; 081704 ;
摘要
The new tris(ferrocenylamine) ditertiary phosphine 1,1'-{FcCH(2)N(CH2PPh(2))CH(2)(eta(5)-C(5)H(4))}(2)Fe [Fc - (eta(5)C(5)H(5)) Fe(eta(5)-C(5)H(4))] has been prepared along with two coordination complexes. All compounds have been characterised by a combination of spectroscopic and analytical methods. The single crystal X-ray structure of the pentametallic Ru(2)Fe(3) complex 5 has been determined. (C) 2010 Elsevier B.V. All rights reserved.
引用
收藏
页码:1838 / 1842
页数:5
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