Synthesis and photophysical properties of conjugated anthracene-based compounds

被引：22

作者：

Marrocchi, Assunta ^{[1
,2
]}

Spalletti, Anna ^{[1
,2
]}

Ciorba, Serena ^{[1
,2
]}

Seri, Mirko ^{[1
]}

Elisei, Fausto ^{[1
,2
]}

Taticchi, Aldo ^{[1
,2
]}

机构：

[1] Univ Perugia, Dept Chem, I-06123 Perugia, PG, Italy

[2] Univ Perugia, CEMIN, I-06123 Perugia, PG, Italy

来源：

JOURNAL OF PHOTOCHEMISTRY AND PHOTOBIOLOGY A-CHEMISTRY | 2010年 / 211卷 / 2-3期

关键词：

Anthracene derivatives; Arylacetylenes; Synthesis; Spectral/photophysical properties; EXCITED-STATE PROPERTIES; FIELD-EFFECT TRANSISTORS; DERIVATIVES;

D O I：

10.1016/j.jphotochem.2010.03.002

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Four novel diarylanthracene derivatives (1, 5a, 5b, 6) have been synthesized by Suzuki and Sonogashira coupling reactions, characterized and their structure assigned by H-1 and C-13 NMR spectroscopy. The spectral and photophysical properties of a series of symmetrically and asymmetrically disubstituted anthracene-based compounds (1-6) and of benzothiadiazole derivative 7 have been studied. All these photostable systems show high fluorescence emission and a batochromic shift of the absorption spectrum that increase with pi-conjugation. Flash photolysis measurements were carried out on the poor fluorescent compound 4. (C) 2010 Elsevier B.V. All rights reserved.

引用

页码：162 / 169

页数：8

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