Copper-containing DNA-Silica Mineral Complexes for the Asymmetric Diels-Alder Reaction

被引：5
|
作者：
Sakashita, Sohei [1 ]
Park, Soyoung [1 ]
Sugiyama, Hiroshi [1 ,2 ]
机构：
[1] Kyoto Univ, Grad Sch Sci, Dept Chem, Sakyo Ku, Kyoto 6068502, Japan
[2] Kyoto Univ, Inst Integrated Cell Mat Sci iCeMS, Sakyo Ku, Kyoto 6068501, Japan
来源：
CHEMISTRY LETTERS | 2017年 / 46卷 / 08期
基金：
日本学术振兴会;
关键词：
DNA-based hybrid catalyst; Asymmetric synthesis; DNA-silica mineral; G-QUADRUPLEX; HELICAL ARCHITECTURES; ORGANIC-SYNTHESIS; HYBRID CATALYSTS; POVAROV REACTION; CHIRAL PACKING; WATER; NANOPARTICLES; ALCOHOLS;
D O I：
10.1246/cl.170411
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
In this study, we have generated DNA-silica minerals containing a Cu(ligand) complex and evaluated their utility in asymmetric synthesis. Cu(dmbpy)/DNA-silica mineral could be applied successfully to the Diels-Alder reaction and reused readily for 10 cycles without loss of enantioselectivity.
引用
收藏
页码：1165 / 1168
页数：4
相关论文
共 50 条
  • [1] HEXACHLOROCYCLOPENTADIENE IN DIELS-ALDER ASYMMETRIC REACTION
    AKHMEDOV, IM
    PEYNIRCIOGLU, B
    MAMEDOV, EG
    TANYELI, C
    DEMIR, AS
    TETRAHEDRON, 1994, 50 (07) : 2099 - 2106
  • [2] COMPLEXES CONTAINING A LEWIS-ACID AND BRONSTED ACID FOR THE CATALYTIC ASYMMETRIC DIELS-ALDER REACTION
    AGGARWAL, VK
    ANDERSON, E
    GILES, R
    ZAPARUCHA, A
    TETRAHEDRON-ASYMMETRY, 1995, 6 (06) : 1301 - 1306
  • [3] Asymmetric catalysis of the Diels-Alder reaction using dicationic zirconocene complexes
    Bondar, GV
    Aldea, R
    Levy, CJ
    Jaquith, JB
    Collins, S
    ORGANOMETALLICS, 2000, 19 (06) : 947 - 949
  • [4] ASYMMETRIC DIELS-ALDER REACTION OF A CHIRAL AZLACTONE
    BUNUEL, E
    CATIVIELA, C
    DIAZDEVILLEGAS, MD
    TETRAHEDRON-ASYMMETRY, 1994, 5 (02) : 157 - 160
  • [5] DIELS-ALDER REACTION IN PARTIAL ASYMMETRIC SYNTHESIS
    KOROLEV, AI
    MUR, VI
    AVAKYAN, VG
    JOURNAL OF GENERAL CHEMISTRY USSR, 1964, 34 (02): : 713 - &
  • [6] PARTIAL ASYMMETRIC SYNTHESES - DIELS-ALDER REACTION
    WALBORSKY, H
    BARASH, L
    DAVIS, TC
    JOURNAL OF ORGANIC CHEMISTRY, 1961, 26 (11): : 4778 - &
  • [7] PARTIAL ASYMMETRIC SYNTHESIS IN DIELS-ALDER REACTION
    WALBORSKY, HM
    DAVIS, TC
    BARASH, L
    TETRAHEDRON, 1963, 19 (12) : 2333 - &
  • [8] Reusable catalysts for the asymmetric Diels-Alder reaction
    Chollet, Guillaume
    Guillerez, Marie-George
    Schulz, Emmanuelle
    CHEMISTRY-A EUROPEAN JOURNAL, 2007, 13 (03) : 992 - 1000
  • [9] A MODEL FOR ASYMMETRIC INDUCTION IN THE DIELS-ALDER REACTION
    TROST, BM
    OKRONGLY, D
    BELLETIRE, JL
    JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1980, 102 (25) : 7595 - 7596
  • [10] Asymmetric catalysis of the transannular Diels-Alder reaction
    Balskus, Emily P.
    Jacobsen, Eric N.
    SCIENCE, 2007, 317 (5845) : 1736 - 1740
12345