A C60-aryne building block: synthesis of a hybrid all-carbon nanostructure

被引:33
|
作者
Garcia, D. [1 ,2 ]
Rodriguez-Perez, L. [3 ]
Herranz, M. A. [3 ]
Pena, D. [1 ,2 ]
Guitian, E. [1 ,2 ]
Bailey, S. [4 ]
Al-Galiby, Q. [4 ,5 ]
Noori, M. [4 ]
Lambert, C. J. [4 ]
Perez, D. [1 ,2 ]
Martin, N. [3 ,6 ]
机构
[1] Univ Santiago de Compostela, Ctr Invest Quim Biolox & Mat Mol CIQUS, Santiago De Compostela 15782, Spain
[2] Univ Santiago de Compostela, Dept Quim Organ, Santiago De Compostela 15782, Spain
[3] Univ Complutense Madrid, Fac Quim, Dept Quim Organ 1, Ave Complutense S-N, E-28040 Madrid, Spain
[4] Univ Lancaster, Dept Phys, Lancaster LA1 4YB, England
[5] Al Qadisiyah Univ, Coll Educ, Dept Phys, Al Diwaniyah, Iraq
[6] IMDEA Nanociencia, C Faraday 9,Campus Cantoblanco, Madrid 28049, Spain
基金
欧洲研究理事会; 英国工程与自然科学研究理事会;
关键词
BENZYNE; ARYNES; CHEMISTRY; CYCLOADDITION; GRAPHENE;
D O I
10.1039/c5cc10462a
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
The synthesis of a [60]fullerene-benzyne building block and its further chemical cycloaddition reaction with graphene has resulted in a new all-carbon hybrid material which has been characterized by TGA, FTIR and Raman spectroscopies, XPS as well as AFM and TEM. Based on computational studies, the formation of both [2+2] and [4+2] cycloadducts on the graphene surface is feasible.
引用
收藏
页码:6677 / 6680
页数:4
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