Silver-mediated intramolecular P-C coupling

被引:0
|
作者
Szaloki, Gyorgy [1 ]
Miqueu, Karinne [2 ]
Bourissou, Didier [1 ]
机构
[1] Univ Toulouse III Paul Sabatier, Lab Heterochim Fondamentale & Appl LHFA, CNRS, UAIR 5069, F-31062 Toulouse 09, France
[2] Univ Pau & Pays Adour, Inst Sci Analyt & Phys Chim Environm & Mat IPREM, CNRS, E2S UPPA,UMR 5254, F-64053 Pau 09, France
关键词
silver; complexes; cross-coupling; oxidative addition; phosphonium salts; DF1; naphthalene; peri substitution;
D O I
10.1016/j.mencom.2022.01.025
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Silver(I) salts mimic copper(I) but not gold(I) salts in the reaction with peri-iodo naphthyldiisopropylphosphine. The formation of the corresponding peri-cyclic phosphonium derivatives represents the first example of silver-mediated P-C coupling through a two-electron redos. sequence.
引用
收藏
页码:78 / 79
页数:2
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