Sonochemical syntheses of xanthene derivatives using zeolite-supported transition metal catalysts in aqueous media

被引：13

作者：

Safa, Kazem D. ^{[1
]}

Taheri, Elham ^{[1
]}

Allahvirdinesbat, Maryam ^{[1
]}

Niaei, Aligholi ^{[2
]}

机构：

[1] Univ Tabriz, Fac Chem, Organosilicon Res Lab, Tabriz 5166614766, Iran

[2] Univ Tabriz, Fac Chem, Dept Appl Chem & Chem Engn, Tabriz 5166614766, Iran

来源：

RESEARCH ON CHEMICAL INTERMEDIATES | 2016年 / 42卷 / 04期

关键词：

Xanthenes; Fe-Cu/ZSM-5; Ultrasonic irradiation; MCRs; Supported catalyst; Water; ONE-POT SYNTHESIS; 1,8-DIOXO-OCTAHYDROXANTHENE DERIVATIVES; EFFICIENT; MULTICOMPONENT; SULFATE; ACID;

D O I：

10.1007/s11164-015-2192-1

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

An efficient green method for the syntheses of biologically active xanthene derivatives by use of zeolite-supported transition metal catalysts is described. A Fe-Cu/ZSM-5 heterogeneous catalyst has the highest activity in the one-pot syntheses with a wide range of aldehydes and cyclic 1,3-diketones, under ultrasonic irradiation in water at ambient temperatures. The three-component condensation in the presence of supported metal catalysts is operationally simple, requires no expensive or toxic reagents, and gives high yields in short reaction times.

引用

页码：2989 / 3004

页数：16

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