Tailoring the optical properties of metal-oxide electrochromic mixtures

被引：5
|
作者：
Monk, PMS [1 ]
Bleazard, S [1 ]
Akhtar, SP [1 ]
Boutevin, J [1 ]
机构：
[1] Manchester Metropolitan Univ, Dept Chem, Manchester M1 5GD, Lancs, England
来源：
PHYSICAL CHEMISTRY CHEMICAL PHYSICS | 2000年 / 2卷 / 19期
关键词：
D O I：
10.1039/b005430p
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
A semi-empirical approach is given to show how an optical-shift parameter S (via the frequency maximum of an optical band) correlates with the composition of a mixture of electrochromic oxides such as tungsten trioxide, thereby allowing the colours of electrochromic oxide mixtures to be tailored. It is shown that changing the relative amounts of charge-donating oxygen-based moieties (oxide, pendant oxygen and bridging oxygen) in the mixture systematically varies the electrochromic colour according to 'shifting constants' sigma, which depend on the identities of both dopant and host oxides.
引用
收藏
页码：4415 / 4419
页数：5
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