(Z)-1-benzoyl-4-tert-butyl-1-methylcyclohexane and (Z)-4-tert-butyl-1-methyl-1-thiobenzoylcyclohexane

被引:4
|
作者
Fu, TY
Leibovitch, M
Scheffer, JR
Trotter, J
机构
[1] Department of Chemistry, University of British Columbia, Vancouver
关键词
D O I
10.1107/S0108270197005283
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Both title molecules, C18H26O and C18H26S, contain six-membered cyclohexane rings with chair conformations, equatorial 1-methyl and 4-tert-butyl substituents, and axial 1-benzoyl or 1-thiobenzoyl substituents, respectively. The substituent carbonyl and thiocarbonyl groups are oriented with the O and S atoms close to axial H atoms in the cyclohexane rings, thus accounting for the observed photochemical reactivity.
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页码:1255 / 1256
页数:2
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