Molecularly imprinted polyamide membranes for chiral recognition

被引：30
|
作者：
Kondo, Y [1 ]
Yoshikawa, M
Okushita, H
机构：
[1] Kyoto Inst Technol, Dept Polymer Sci & Engn, Kyoto 6068585, Japan
[2] Ube Ind Ltd, Polymer Lab, Ube, Yamaguchi 7558633, Japan
来源：
POLYMER BULLETIN | 2000年 / 44卷 / 5-6期
关键词：
Separation Factor; Polymeric Membrane; Absolute Configuration; Hexamethylene; Chiral Recognition;
D O I：
10.1007/s002890070073
中图分类号：
O63 [高分子化学（高聚物）];
学科分类号：
070305 ; 080501 ; 081704 ;
摘要：
Molecularly imprinted polymeric membranes were prepared from amorphous poly(hexamethylene terephthalamide/isophthalamide). Membranes imprinted bq Z-D-Glu recognize the D-isomer, of which absolute configuration is the same as that of the print molecule, in preference to the corresponding L-isomer, and vice versa. The amino acid preferentially. adsorbed by the membrane was also selectively permeated by electrodialysis. An optimum separation factor of 2.0 was reached at the applied potential difference of 2.0 V.
引用
收藏
页码：517 / 524
页数：8
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