Methacrylonitrile-vinylidene chloride-butyl acrylate terpolymers: Monomer sequence determination by one- and two-dimensional NMR spectroscopy

被引：0

作者：

Brar, AS ^{[1
]}

Pradhan, DR ^{[1
]}

Hooda, S ^{[1
]}

机构：

[1] Indian Inst Technol, Dept Chem, New Delhi 110016, India

来源：

INDIAN JOURNAL OF CHEMISTRY SECTION A-INORGANIC BIO-INORGANIC PHYSICAL THEORETICAL & ANALYTICAL CHEMISTRY | 2004年 / 43卷 / 10期

关键词：

D O I：

暂无

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Methacrylonitrile-vinylidene chloride-butyl acrylate (M/V/B) terpolymers of different composition have been prepared by bulk polymerization using benzoyl peroxide as an initiator. The terpolymer compositions have been determined from quantitative assessment of the respective C-13{H-1} NMR spectra and the observed values compared with the theoretical values obtained from Alfrey-Goldfinger's equation. The overlapping methine and methylene carbon resonances of terpolymers have been differentiated by DEPT experiments. The quaternary carbon resonances of M/V/B terpolymers have been assigned to triad compositional sequences. The complete H-1 and C-13{H-1} NMR spectra of terpolymers have been assigned without ambiguity with the help of 2D HSQC NMR spectroscopic techniques.

引用

页码：2066 / 2072

页数：7

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