Synthesis and Characterization of New Chlorocarbonylrhenium(I) Complexes with P-Donor Chelate Ligands

被引：0
|
作者：
Bolano, Sandra [1 ]
Bravo, Jorge [1 ]
Castro, Jesus [1 ]
Garcia-Fontan, Soledad [1 ]
Carmen Marin, M. [1 ]
机构：
[1] Univ Vigo, Dept Quim Inorgan, Fac Quim, Vigo 36310, Spain
来源：
ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE | 2010年 / 636卷 / 3-4期
关键词：
Carbonyl ligands; Chlorine; P ligands; Rhenium; NMR spectroscopy; PROTONATION REACTIONS; CRYSTAL-STRUCTURE; NITROXYL HN=O; RHENIUM; MANGANESE; CARBONYL; HYDROXYLAMINE; DERIVATIVES; REACTIVITY; CATALYSIS;
D O I：
10.1002/zaac.200900390
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
Chlorocarbonylrhenium(I) complexes fac.cis-[ReCl(CO)(3)L1-3] [L-1 = Ph2PO(CH2)(2)OPPh2 (1); L-2 = Ph2PO(CH2)(3)OPPh2 (2); L-3 = iPr(2)PO(CH2)(2)OPiPr(2) (3)] were synthesized by reaction of [ReCl(CO)(5)] with the appropriate diphosphinite ligands L1-3. Reaction of met;cis-[ReH(CO)(3)L-2] with HCl affords an isomer of compound 2, the complex mercis-[ReCl(CO)(3)L-2] (4). The new complexes were characterized by IR, H-1, C-13{H-1} and P-31{H-1} NMR spectroscopy and in the case of complexes 2 and 4 by single-crystal X-ray structure determination.
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收藏
页码：506 / 510
页数：5
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