β-cyclodextrin-polyelectrolyte interactions in aqueous solution:: I.: Poly(4-sodium styrenesulfonate) (NaPSS)

被引：8
|
作者：
Leclercq, L
Bria, M
Morcellet, M
Martel, B
机构：
[1] Univ Sci & Technol Lille, Lab Chim Macromol, CNRS, UA 351, F-59655 Villeneuve Dascq, France
[2] Univ Sci & Technol Lille, Chim Phys Organ Lab, CNRS, UA 351, F-59655 Villeneuve Dascq, France
来源：
JOURNAL OF INCLUSION PHENOMENA AND MOLECULAR RECOGNITION IN CHEMISTRY | 1998年 / 30卷 / 03期
关键词：
beta-cyclodextrin; inclusion complexes; polymer; viscosimetry; circular dichroism; NMR spectroscopy; thermogravimetric analyses;
D O I：
10.1023/A:1007956624986
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
The interactions between beta-cyclodextrin and a hydrosoluble polymer carrying hydrophobic residues: poly(4-sodium styrenesulfonate) have been studied. Several techniques were used: capillary viscosimetry, circular dichroism, and NMR spectroscopy. The results proved that the aromatic residues of NaPSS were included in the cavity of beta-cyclodextrin and that, in addition, a network of hydrogen bonding between sulfonic acid residues and the hydroxyl groups of beta-cyclodextrin occured.
引用
收藏
页码：215 / 225
页数：11
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