Unprecedented cesium and potassium fluorides catalyzed trialkylsilylation and tributylstannylation of terminal alkynes with trifluoromethyl-trialkylsilanes and -tributylstannane

被引：37

作者：

Ishizaki, M ^{[1
]}

Hoshino, O ^{[1
]}

机构：

[1] Sci Univ Tokyo, Fac Pharmaceut Sci, Shinjuku Ku, Tokyo 1620826, Japan

来源：

TETRAHEDRON | 2000年 / 56卷 / 45期

关键词：

1-alkyne; trialkylsilylation; tributylstannylation; cesium fluoride; potassium fluoride;

D O I：

10.1016/S0040-4020(00)00810-3

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Cesium and potassium fluorides promoted trialkylsilylation and tributylstannylation of terminal alkynes with trifluoromethyltrialkylsilanes and -tributylstannane were found to give 1-silyl- and 1-tributylatannyl-alkynes in high yield. The present reactions are applicable to 1-alkynes having a wide range of functional groups such as acetal, iodo, silyl, amino, amido and carbonyl (except for aldehyde) groups. (C) 2000 Elsevier Science Ltd. All rights reserved.

引用

页码：8813 / 8819

页数：7