The thermal stability of lithium-manganese-oxide spinel phases

被引：130
|
作者：
Thackeray, MM
Mansuetto, MF
Dees, DW
Vissers, DR
机构：
[1] Electrochemical Technology Program, Chemical Technology Division, Argonne National Laboratory, Argonne, IL 60439
来源：
MATERIALS RESEARCH BULLETIN | 1996年 / 31卷 / 02期
关键词：
oxides; thermogravimetric analysis (TGA); X-ray diffraction; electrochemical properties;
D O I：
10.1016/0025-5408(95)00190-5
中图分类号：
T [工业技术];
学科分类号：
08 ;
摘要：
The thermal stability of stoichiometric spinel phases in the system Li1+deltaMn2-deltaO4 (0 less than or equal to delta less than or equal to 0.33) has been investigated by high-temperature powder X-ray diffraction, differential thermal analysis, and thermogravimetric analysis. At elevated temperatures, the lithium-manganese-oxide spinels undergo phase changes by loss of oxygen and lithia (Li2O). The data highlight the importance of temperature control when synthesising lithium-manganese-oxide spinel compounds.
引用
收藏
页码：133 / 140
页数：8
相关论文
共 50 条
  • [1] In Situ Atom Probe Deintercalation of Lithium-Manganese-Oxide
    Pfeiffer, Bjoern
    Maier, Johannes
    Arlt, Jonas
    Nowak, Carsten
    [J]. MICROSCOPY AND MICROANALYSIS, 2017, 23 (02) : 314 - 320
  • [2] STRUCTURAL ASPECTS OF LITHIUM-MANGANESE-OXIDE ELECTRODES FOR RECHARGEABLE LITHIUM BATTERIES
    ROSSOUW, MH
    DEKOCK, A
    DEPICCIOTTO, LA
    THACKERAY, MM
    [J]. MATERIALS RESEARCH BULLETIN, 1990, 25 (02) : 173 - 182
  • [3] Structural stability in partially substituted lithium manganese spinel oxide cathode
    Masataka Wakihara
    Hiromasa Ikuta
    Yoshiharu Uchimoto
    [J]. Ionics, 2002, 8 : 329 - 338
  • [4] Structural Stability in Partially Substituted Lithium Manganese Spinel Oxide Cathode
    Wakihara, Masataka
    Ikuta, Hiromasa
    Uchimoto, Yoshiharu
    [J]. IONICS, 2002, 8 (5-6) : 329 - 338
  • [5] SYNTHESIS AND STRUCTURAL CHARACTERIZATION OF DEFECT SPINELS IN THE LITHIUM-MANGANESE-OXIDE SYSTEM
    THACKERAY, MM
    DEKOCK, A
    DAVID, WIF
    [J]. MATERIALS RESEARCH BULLETIN, 1993, 28 (10) : 1041 - 1049
  • [6] Performance and characterization of lithium-manganese-oxide cathode material with large tunnel structure for lithium batteries
    Yang, Y
    Shu, D
    You, JK
    Lin, ZG
    [J]. JOURNAL OF POWER SOURCES, 1999, 81 : 637 - 641
  • [7] Chemical syntheses of nanocrystalline lithium manganese oxide spinel
    Michalska, Monika
    Lipinska, Ludwika
    Diduszko, Ryszard
    Mazurkiewicz, Marta
    Malolepszy, Artur
    Stobinski, Leszek
    Kurzydlowski, Krzysztof J.
    [J]. PHYSICA STATUS SOLIDI C: CURRENT TOPICS IN SOLID STATE PHYSICS, VOL 8, NO 7-8, 2011, 8 (7-8): : 2538 - 2541
  • [8] Electrochemical and calorimetric approach to spinel lithium manganese oxide
    Kobayashi, Y
    Kihira, N
    Takei, K
    Miyashiro, H
    Kumai, K
    Terada, N
    Ishikawa, R
    [J]. JOURNAL OF POWER SOURCES, 1999, 81 : 463 - 466
  • [9] Hydrothermal synthesis of nanostructured spinel lithium manganese oxide
    Liu, ZQ
    Wang, WI
    Liu, XM
    Wu, MC
    Li, D
    Zeng, Z
    [J]. JOURNAL OF SOLID STATE CHEMISTRY, 2004, 177 (4-5) : 1585 - 1591
  • [10] The influence of doping on the operation of lithium manganese oxide spinel
    Wohlfahrt-Mehrens, M
    Butz, A
    Oesten, R
    Arnold, G
    Hemmer, RP
    Huggins, RA
    [J]. JOURNAL OF POWER SOURCES, 1997, 68 (02) : 582 - 585
12345