Synthesis and crystal structure of [2-dapp]2[Zn(dmit)2] (2-dapp=2-(4-dimethylaminophenyl)ethyl-1-methylpyridinium, dmit=1,3-dithiole-2-thione-4,5-dithiolato)

被引：0
|
作者：
Yang, YH
Wang, SN
Wang, W
Fun, HK
You, XZ
Bai, JF [1 ]
机构：
[1] Nanjing Univ, Inst Coordinat Chem, State Key Lab Coordinat Chem, Nanjing 210093, Peoples R China
[2] Univ Sains Malaysia, Sch Phys, Xray Crystallog Unit, George Town 11800, Malaysia
来源：
CHINESE JOURNAL OF STRUCTURAL CHEMISTRY | 2004年 / 23卷 / 11期
关键词：
crystal structure; zinc; dapp; dmit;
D O I：
暂无
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
The title compound [2-dapp](2)[Zn(dmit)(2)] synthesized by, the direct reaction of [Et4N](2)[Zn(dmit)(2)] and [2-dapp]I crystallizes in monoclinic, space group P2(1)/c with a = 29.7436(6), b = 10.6266(3), c = 13.6161(4) Angstrom, beta = 93.116(1)degrees, V = 4297.3 Angstrom(3), Z = 4, D-c = 1.448 g/cm(3), mu = 1.091 mm(-1) and F(000) = 1936. The structure was refined by full-matrix least-squares methods to the final R = 0.075 and wR = 0.116, revealing the zinc-bis (dmit) anions interact strongly with the planar cation, 2-dapp(+), by the hydrogen bond C(l)-H(lC)S-...(7) (x, 3/2-y, -1/2+z).
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页码：1242 / 1245
页数：4
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