Selective oxidation of 5-hydroxymethyl-2-furfural to furan-2,5-dicarboxylic acid over spinel mixed metal oxide catalyst

被引：71
|
作者：
Jain, Archana [1 ]
Jonnalagadda, Subash C. [1 ]
Ramanujachary, Kandalam V. [1 ]
Mugweru, Amos [1 ]
机构：
[1] Rowan Univ, Dept Chem & Biochem, Glassboro, NJ 08028 USA
来源：
CATALYSIS COMMUNICATIONS | 2015年 / 58卷
关键词：
Spinel Li2CoMn3O8; Selective oxidation; 5-Hydroxymethyl-2-furfural (HMF); Furan-2,5-dicarboxylic acid (FDCA); 2,5-FURANDICARBOXYLIC ACID; AEROBIC OXIDATION; BIOMASS; CONVERSION; CHEMICALS; FUELS;
D O I：
10.1016/j.catcom.2014.09.017
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
Furan-2,5-dicarboxylic acid (FDCA) is a potential platform chemical in polymer industry for manufacturing polyester, polyamides and polyurethanes. Here, we introduced Li2CoMn3O8 as an efficient catalyst for the selective oxidation of 5-hydroxymethyl-2-furfural (HMF) to FDCA with 80% isolated yield in a gram scale reaction. The nanocrystalline spinel Li2CoMn3O8 catalyst was synthesized by gel pyrolysis method using urea and citric acid as complexing agent. The catalyst was characterized using PXRD, BET, ICP-MS and TEM. The catalyst is cheap and easy to prepare. The use of naturally abundant oxygen as oxidant results to high isolated product yield making this procedure scalable. (C) 2014 Elsevier B.V. All rights reserved.
引用
收藏
页码：179 / 182
页数：4
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