One-dimensional hydrogen-bonded polymer based on tetra-iso-butyl-resorcin[4]arene and 2,6-diacetylpyridine

被引：0

作者：

Liu, SQ ^{[1
]}

Yao, WR ^{[1
]}

Zhang, QF ^{[1
]}

机构：

[1] Anhui Univ Technol, Sch Chem Engn & Chen, Dept Appl Chem, Maanshan 243002, Anhui, Peoples R China

来源：

CHINESE JOURNAL OF STRUCTURAL CHEMISTRY | 2005年 / 24卷 / 01期

关键词：

resorcinarene; hydrogen-bonding; supramolecular chemistry;

D O I：

暂无

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The co-crystallization of tetra-iso-butyl-resorcin[4]arene I and 2,6-diacetyl-pyridine (Ac(2)py) from MeCN/CH2Cl2 yielded a multi-component complex 1-Ac(2)py-2H(2)O.0.5Me-CN 2, in which the upper rim of 1 is extended supramolecularly by way of hydrogen bonds. Complex 2 (C52H66.5N1.5O14) crystallizes in monoclinic, space group P2(1)/m with a = 10.845(9), b = 20.805(17), c = 12.881 (11) Angstrom, beta = 103.884(19)degrees, V = 2821(4) Angstrom(3), D-c = 1. 102 g/cm(3) and Z = 2. The molecular structure shows that the two adjacent double-stranded arrays as well as linear and zigzag chains generated from Ac(2)py and water bridging to two resorcin[4] arene molecules, respectively, facilitate self-inclusion of one-dimensional hydrogen-bonded polymer.

引用

页码：99 / 103

页数：5

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