Organic synthesis in ionic liquids: The Stille coupling

被引：171
|
作者：
Handy, ST [1 ]
Zhang, XL [1 ]
机构：
[1] SUNY Binghamton, Dept Chem, Binghamton, NY 13902 USA
来源：
ORGANIC LETTERS | 2001年 / 3卷 / 02期
关键词：
D O I：
10.1021/ol0068849
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
[GRAPHICS] The Stille coupling reaction has been performed in 1-butyl-3-methylimidazolium tetrafluoroborate (BMIM BF4), a room temperature ionic liquid (RTIL). Use of this solvent system allows for facile recycling of the solvent and catalyst system, which can be used at least five times with little loss in activity. An interesting preference in starting catalyst oxidation state for use with aryl bromides and aryl iodides was observed.
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页码：233 / 236
页数：4
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