Synthesis and mesomorphism of γ-substituted β-diketonate dicarbonylrhodium(I) complexes

被引:0
|
作者
Wan, W [1 ]
Zhao, KQ [1 ]
Guan, WJ [1 ]
Yang, LM [1 ]
Zhang, LF [1 ]
机构
[1] Chinese Acad Sci, Chengdu Inst Organ Chem, Chengdu 610041, Peoples R China
关键词
organometal; complex; liquid crystal; beta-diketoate;
D O I
暂无
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Rodlike organometallic liquid crystals of gamma - substituted beta - diketonate dicarbonyl rhodium(I) complexes containing one or two benzene rings were synthesized and characterized. The effects of rigid cores, structure and the ratio of molecular length to width on the liquid crystalline properties were also studied. The results show that the model design of nematic organic liquid crystal can also direct the molecular design and synthesis of organometallic liquid crystals.
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页码:278 / 283
页数:6
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