Fashionably Late: Synthesis and Characterization of Transition-Metal-Fluoroborylene Complexes

被引：12

作者：

Braunschweig, Holger ^{[1
]}

Dewhurst, Rian D. ^{[1
]}

机构：

[1] Univ Wurzburg, Inst Anorgan Chem, D-97074 Wurzburg, Germany

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2010年 / 49卷 / 20期

关键词：

boron; borylene complexes; Group; 4; metals; matrix isolation; ruthenium; BORON-FLUORINE CHEMISTRY; BORYLENE COMPLEXES; COORDINATION; REACTIVITY; LIGAND; BF; SUBSTITUTION; MONOFLUORIDE; CO;

D O I：

10.1002/anie.201000841

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Chemical equation presentation. B and F become BFFs: The last of the neutral first-row main group diatomics, BF, has conspicuously eluded synthetic chemists and their attempts to stabilize it by transition metals. After decades of near misses, two contrasting families of fluoroborylene transition metal complexes have been definitively synthesized by the research groups of Aldridge and Andrews. © 2010 Wiley-VCH Verlag GmbH & Co. KGaA,.

引用

页码：3412 / 3414

页数：3

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