Metal enrichment in the groundwater of the arid environment in South Africa

This paper presents the enrichment tendency and spatial distribution of metals in the groundwater which is pumped out from the granitic aquifers in South Africa. Groundwater is the sole source of water supply for the local community in the study area (Namaqualand), and hence, it was necessary to understand the controlling geochemical processes and interrelationship of metals in the groundwater. The geochemical association of metals has been assessed based on the geostatistical methods. The results show that geochemical processes such as oxidation, leaching, and evaporation besides water-rock interaction are very important in controlling metal enrichment in the groundwater from highly mineralized rocks. The metal enrichment index for selected toxic metals in groundwater increases in the order of Cd > U > Cr > Pb. The observed enrichment trend could be considered as a result of mineralization of basement rocks which is facilitated by active geochemical process in the arid environment. The lack of aquifer flushing due to negligible recharge helps the metals to concentrate at shallow groundwater zones supported by severe evaporation process.