Theory of spontaneous polarization of endohedral fullerenes

被引：8
|
作者：
Clougherty, DP [1 ]
Anderson, FG [1 ]
机构：
[1] Univ Vermont, Dept Phys, Burlington, VT 05405 USA
来源：
PHYSICAL REVIEW LETTERS | 1998年 / 80卷 / 17期
关键词：
D O I：
10.1103/PhysRevLett.80.3735
中图分类号：
O4 [物理学];
学科分类号：
0702 ;
摘要：
A pseudo-Jahn-Teller model describing central atom distortions is proposed for endohedral fullerenes of the form A@C-60 where A is either a rare gas or a metal atom. A critical (dimensionless) coupling g(c) is found, below which the symmetric configuration is stable and above which inversion symmetry is broken. Vibronic parameters are given for selected endohedral fullerenes.
引用
收藏
页码：3735 / 3738
页数：4
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