Solvothermal Syntheses and Crystal Structures of Two Thiostannates(IV) [M(tepa)]2(μ-Sn2S6) (M = Fe2+ and Co2+)

被引：17
|
作者：
Zhang, Yong [2 ]
Zhou, Jian [3 ]
Tang, Ai-Bin [2 ]
Bian, Guo-Qing [2 ]
Dai, Jie [1 ,2 ]
机构：
[1] Soochow Univ, Dept Chem, Suzhou 215123, Peoples R China
[2] Soochow Univ, Key Lab Organ Synth Jiangsu Prov, Suzhou 215123, Peoples R China
[3] Yulin Normal Univ, Dept Biol & Chem, Yulin 537000, Peoples R China
来源：
JOURNAL OF CHEMICAL CRYSTALLOGRAPHY | 2010年 / 40卷 / 06期
关键词：
Solvothermal synthesis; Thiostannates; Crystal structures; Transition metals; Amine; ELECTRONIC-PROPERTIES; TIN SULFIDE; TE ANIONS; TERNARY; ZN; CHALCOGENIDE; REACTIVITY; COMPOUND; DISCRETE; CLUSTERS;
D O I：
10.1007/s10870-009-9684-z
中图分类号：
O7 [晶体学];
学科分类号：
0702 ; 070205 ; 0703 ; 080501 ;
摘要：
Two new thiostannates [M(tepa)](2)(mu-Sn2S6) (tepa = tetraethylenepentamine, M = Fe2+ 1 and Co2+ 2) were prepared by solvothermal method. Compounds 1 and 2 are isostructural. Both the compounds crystallize in the tetragonal system, space group I41/a (no. 88) with the crystal parameters of 1: a = 25.683(2) angstrom, b = 25.683(2) angstrom, c = 9.9860(9) angstrom, V = 6,586.7(11) angstrom(3), Z = 8, and 2: a = 25.742(3) angstrom, b = 25.742(3) angstrom, c = 9.8977(12) angstrom, V = 6,558.5(14) angstrom(3), Z = 8. The Sn2S64- anion acts as a bidentate bridging ligand connecting two transition metal complex cations by trans terminal S atoms to form neutral centro-symmetric [M(tepa)]2(mu-Sn2S6) moieties.
引用
收藏
页码：496 / 500
页数：5
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