Imaging MoS2 Nanocatalysts with Single-Atom Sensitivity

被引:83
|
作者
Kisielowski, Christian [2 ]
Ramasse, Quentin M. [2 ]
Hansen, Lars P. [1 ]
Brorson, Michael [1 ]
Carlsson, Anna [3 ]
Molenbroek, Alfons M. [1 ]
Topsoe, Henrik [1 ]
Helveg, Stig [1 ]
机构
[1] Haldor Topsoe Res Labs, DK-2800 Lyngby, Denmark
[2] Univ Calif Berkeley, Lawrence Berkeley Lab, Natl Ctr Electron Microscopy, Berkeley, CA 94708 USA
[3] FEI Co, NL-5651 GG Eindhoven, Netherlands
关键词
chalcogens; electron microscopy; heterogeneous catalysis; molybdenum; single-atom imaging; FULLERENE-LIKE NANOPARTICLES; HYDROTREATING CATALYSTS; INORGANIC NANOTUBES; S NANOCLUSTERS; MORPHOLOGY; MICROSCOPY; RESOLUTION; SITES;
D O I
10.1002/anie.200906752
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
(Figure Presented) Close up: The atomic arrangement of industrial-style MoS2 nanocatalysts can be scrutinized by using single-atom-sensitive electron microscopy (see picture). This technique, which provides an excellent agreement between simulation and experiment, allows element detection in compound materials and permits the type and the concentration of the catalytically important edge sites to be estimated. © 2010 Wiley-VCH Verlag GmbH & Co. KGaA.
引用
收藏
页码:2708 / 2710
页数:3
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