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Non-enzymatic glucose sensor with high sensitivity based on Cu-Al layered double hydroxides
被引:63
|作者:
Wang, Fenfen
[1
]
Zhang, Yanwu
[1
]
Liang, Wenxia
[1
]
Chen, Langxing
[1
,2
]
Li, Yijun
[1
,2
,3
]
He, Xiwen
[1
]
机构:
[1] Nankai Univ, Coll Chem, Tianjin Key Lab Biosensing & Mol Recognit, Tianjin 300071, Peoples R China
[2] Collaborat Innovat Ctr Chem Sci & Engn Tianjin, Tianjin 300071, Peoples R China
[3] Nankai Univ, Natl Demonstrat Ctr Expt Chem Educ, Tianjin 300071, Peoples R China
来源:
关键词:
Cu-Al layered double hydroxides;
Non-enzymatic;
Glucose sensor;
Amperometry;
Blood;
GLASSY-CARBON ELECTRODE;
HYDROGEN-PEROXIDE;
ELECTROCHEMICAL DETECTION;
MESOPOROUS CARBON;
NANOPARTICLES;
NANOCOMPOSITES;
NANOTUBES;
NI/AL;
ARRAY;
H2O2;
D O I:
10.1016/j.snb.2018.06.038
中图分类号:
O65 [分析化学];
学科分类号:
070302 ;
081704 ;
摘要:
The Cu-Al layered double hydroxides (CuAl-LDHs) composites were prepared via one-step co-precipitation method and characterized by scanning electron microscopy (SEM), X-ray diffraction (XRD) and X-ray photoelectron spectroscopy (XPS). Glucose could be oxidized electrocatalytically on the CuAl-LDHs composites modified glassy carbon electrode(CuAl-LDHs/GCE) in alkaline solutions as an enzyme-free sensor with high sensitivity (detection limit of 0.02 mu mol L-1), fast response (less than 5 s) and wide linear range (0.1-240 mu mol L-1). Furthermore, the proposed sensor showed strong anti-interference ability in the presence of dopamine, ascorbic acid, uric acid, acetaminophen and other carbohydrate compounds. The CuAl-LDHs/GCE was used successfully for the determination of glucose in human blood samples.
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页码:41 / 47
页数:7
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