Prussian blue modified FePt nanoparticles for the electrochemical reduction of H2O2

被引：1
|
作者：
Arun, T. [1 ,2 ]
Joseyphus, R. Justin [1 ]
机构：
[1] Natl Inst Technol, Dept Phys, Magnet Mat Lab, Tiruchirappalli 620015, Tamil Nadu, India
[2] Inst Phys, Sachivalaya Marg, Bhubaneswar 751005, Odisha, India
来源：
IONICS | 2016年 / 22卷 / 06期
关键词：
FePt; Prussian blue; Polyol process; Electrocatalytic activity; Magnetic nanoparticles; IRON-OXIDE NANOPARTICLES; HYDROGEN-PEROXIDE; MAGNETIC NANOPARTICLES; POLYOL PROCESS; PD-PT; SURFACE; WATER; EXCHANGE; SILICA; FILM;
D O I：
10.1007/s11581-015-1617-6
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
FePt nanoparticles were synthesized by polyol process with chloride salts, and the equiatomic composition was surface modified with prussian blue (PB). From the magnetic studies, the fraction of PB present in the surface-modified fcc-FePt was found to be 18 %. The FePt nanoparticles with an average particle size of 5 nm forms cluster like morphology, which were embedded in the PB matrix. The electrocatalytic reduction of hydrogen peroxide (H2O2) by the PB-modified FePt nanoparticles was studied. The reduction peak current showed linear response for H2O2 in the concentration range up to 3.5 mM. The FePt nanoparticles did not exhibit significant H2O2 reduction whereas the PB-modified FePt showed reduction of H2O2 with the addition of 0.35 mM of H2O2.
引用
收藏
页码：877 / 883
页数：7
相关论文
共 50 条
  • [1] Prussian blue modified FePt nanoparticles for the electrochemical reduction of H2O2
    T. Arun
    R. Justin Joseyphus
    [J]. Ionics, 2016, 22 : 877 - 883
  • [2] On the mechanism of H2O2 reduction at Prussian Blue modified electrodes
    Faculty of Chemistry, M.V. Lomonosov Moscow Stt. U., Moscow, Russia
    不详
    [J]. Electrochem. Commun., 2 (78-82):
  • [3] On the mechanism of H2O2 reduction at Prussian Blue modified electrodes
    Karyakin, AA
    Karyakina, EE
    Gorton, L
    [J]. ELECTROCHEMISTRY COMMUNICATIONS, 1999, 1 (02) : 78 - 82
  • [4] Synthesis and characterization of Prussian Blue modified magnetite nanoparticles and its application to the electrocatalytic reduction of H2O2
    Zhao, G
    Feng, JJ
    Zhang, QL
    Li, SP
    Chen, HY
    [J]. CHEMISTRY OF MATERIALS, 2005, 17 (12) : 3154 - 3159
  • [5] Synthesis, characterization, and immobilization of prussian blue-modified Au nanoparticles:: Application to electrocatalytic reduction of H2O2
    Qiu, Jian-Ding
    Peng, Hong-Zhen
    Liang, Ru-Ping
    Li, Jian
    Xia, Xing-Hua
    [J]. LANGMUIR, 2007, 23 (04) : 2133 - 2137
  • [6] Prussian Blue modified boron-doped diamond interfaces for advanced H2O2 electrochemical sensors
    Komkova, Maria A.
    Pasquarelli, Alberto
    Andreev, Egor A.
    Galushin, Andrei A.
    Karyakin, Arkady A.
    [J]. ELECTROCHIMICA ACTA, 2020, 339
  • [7] Investigations of Electrodes Modified with Prussian Blue for Highly Sensitive Detection of H2O2
    Rabbow, Thomas
    Schneider, Michael
    Michaelis, Alexander
    Decker, Manfred
    Vonau, Winfried
    Konat-Stepowicz, Joanna
    Eichler, Ruediger
    [J]. TM-TECHNISCHES MESSEN, 2013, 80 (7-8) : 229 - 235
  • [8] Fabrication of graphene/prussian blue composite nanosheets and their electrocatalytic reduction of H2O2
    Jin, E.
    Lu, Xiaofeng
    Cui, Lili
    Chao, Danming
    Wang, Ce
    [J]. ELECTROCHIMICA ACTA, 2010, 55 (24) : 7230 - 7234
  • [9] Electrochemical sensor based on Prussian blue nanorods and gold nanochains for the determination of H2O2
    Shihong Chen
    Liping Ma
    Ruo Yuan
    Yaqin Chai
    Yun Xiang
    Chengyan Wang
    [J]. European Food Research and Technology, 2011, 232 : 87 - 95
  • [10] Electrochemical sensor based on Prussian blue nanorods and gold nanochains for the determination of H2O2
    Chen, Shihong
    Ma, Liping
    Yuan, Ruo
    Chai, Yaqin
    Xiang, Yun
    Wang, Chengyan
    [J]. EUROPEAN FOOD RESEARCH AND TECHNOLOGY, 2011, 232 (01) : 87 - 95
12345