Bis(guanidinium) diaquapentakis(nitrato-κ2O,O′)-lanthanum

被引：3
|
作者：
Fowkes, A [1 ]
Harrison, WTA [1 ]
机构：
[1] Univ Aberdeen, Dept Chem, Aberdeen AB24 3UE, Scotland
来源：
ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS | 2004年 / 60卷
关键词：
D O I：
10.1107/S1600536804025255
中图分类号：
O7 [晶体学];
学科分类号：
0702 ; 070205 ; 0703 ; 080501 ;
摘要：
The title compound, (CH6N3)(2)[La(NO3)(5)(H2O)(2)], contains a network of guanidinium cations and the previously unseen diaquapentakis(nitrato)lanthanum dianion, in which 12 O atoms surround La in a distorted icosahedral arrangement. A network of N-H...O and O-H...O hydrogen bonds helps to consolidate the crystal packing, resulting in a three-dimensional network. The La cation, one N atom and one O atom occupy a twofold axis.
引用
收藏
页码：M1647 / M1649
页数：3
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