Designer ligands. Part 15. Synthesis and characterisation of novel Mn(II), Ni(II) and Zn(II) complexes of 1,10-phenanthroline-derived ligands

被引：4

作者：

Wellington, Kevin W. ^{[2
]}

Kaye, Perry T. ^{[1
]}

Watkins, Gareth M. ^{[1
]}

机构：

[1] Rhodes Univ, Dept Chem, POB 94, ZA-6140 Grahamstown, South Africa

[2] CSIR Biosci, ZA-1645 Modderfontein, South Africa

来源：

ARKIVOC | 2009年

基金：

新加坡国家研究基金会;

关键词：

Manganese(II); nickel(II) and zinc(II) complexes; mononuclear; dinuclear; biomimetic; ligands; catecholase activity; CRYSTAL-STRUCTURE; LACTOBACILLUS-PLANTARUM; DINUCLEAR NICKEL(II); ACTIVE-SITE; MANGANESE; MONONUCLEAR; 3,5-DI-TERT-BUTYLCATECHOL; PSEUDOCATALASE; COORDINATION; OXIDATION;

D O I：

10.3998/ark.5550190.0010.e25

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Series of manganese(II), nickel(II) and zinc(II) complexes have been prepared using 1,10-phenanthroline-derived ligands, and their coordination geometries have been assigned using infrared data. It is apparent that, depending on the ligand, the metal centres adopt octahedral, tetrahedral and distorted tetrahedral coordination geometries. The catecholase activity of the manganese(II) complexes has also been investigated.

引用

页码：301 / 313

页数：13

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