Unexpected P-Si or P-C bond cleavage in the reaction of Li2[(C5Me4)SiMe2-PR] (R = cyclohexyl, 2,4,6-Me3C6H2) and Li[(C5H4)CMe2-PHR] (R = Ph, tBu) with ZrCl4 or [TiCl3(thf)3]:: Formation and molecular structure of the ansa-metallocenes [{(η-C5Me4)2SiMe2}ZrCl2] and [{(η-C5H4)2CMe2}MCl2](M = Ti, Zr) (vol 19, pg 2559, 2000)

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作者：

Koch, T

Blaurock, S

Somoza, FB

Voigt, A

Kirmse, R

Hey-Hawkins, E

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来源：

ORGANOMETALLICS | 2000年 / 19卷 / 20期

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D O I：

10.1021/om000690f

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

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页码：4186 / 4186

页数：1

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[1] Unexpected P-Si or P-C bond cleavage in the reaction of Li2[(C5Me4)SiMe2PR] (R = cyclohexyl, 2,4,6-Me3C6H2) and Li [(C5H4)CMe2PHR] (R = Ph, tBu) with ZrCl4 or [TiCl3(thf)3]:: Formation and molecular structure of the ansa-metallocenes [{(η-C5Me4)2SiMe2}ZrCl2] and [{(η-C5H4)2CMe2}MCl2] (M = Ti, Zr)
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