Palladium-catalysed Suzuki reaction of aryl chlorides in aqueous media using 1,3-dialkylimidazolidin-2-ylidene ligands

被引:47
|
作者
Özdemir, I [1 ]
Demir, S
Yasar, S
Çetinkaya, B
机构
[1] Inonu Univ, Fac Sci & Arts, Dept Chem, TR-44280 Malatya, Turkey
[2] Ege Univ, Dept Chem, TR-35100 Izmir, Turkey
关键词
palladium; imidazolidin-2-ylidene; aryl halides; phenylboronic acid; Suzuki coupling;
D O I
10.1002/aoc.793
中图分类号
O69 [应用化学];
学科分类号
081704 ;
摘要
A highly effective, easy to handle and environmentally benign process for palladium-mediated Suzuki cross-coupling is developed. The in situ prepared three-component system Pd(OAC)(2)-1,3bis(alkyl)imidazolinium chlorides (2a-f) and CS2CO3 catalyses quantitatively the Suzuki crosscoupling of deactivated aryl chlorides. Copyright (C) 2004 John Wiley Sons, Ltd.
引用
收藏
页码:55 / 58
页数:4
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