Influence of acid-base properties of catalysts in the gas-phase dehydration-dehydrogenation of cyclohexanol on amorphous AlPO4 and several inorganic solids

被引：68

作者：

Bautista, FM ^{[1
]}

Campelo, JM ^{[1
]}

García, A ^{[1
]}

Luna, D ^{[1
]}

Marinas, JM ^{[1
]}

Quirós, RA ^{[1
]}

Romero, AA ^{[1
]}

机构：

[1] Univ Cordoba, Fac Ciencias, Dept Quim Organ, E-14014 Cordoba, Spain

来源：

APPLIED CATALYSIS A-GENERAL | 2003年 / 243卷 / 01期

关键词：

cyclohexanol conversion; acid-base sites; amorphous AlPO4 catalyst;

D O I：

10.1016/S0926-860X(02)00540-9

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

A series of metal phosphates (Al, Fe, Ni, Ca and Mn) and stoichiometric (Al/Fe = Al/Ca = 1) mixed systems: FeAl(PO4)(2) and Ca3Al3(PO4)(5), were prepared by an ammonia gelation method. Their amorphous character was determined through several physical methods: nitrogen adsorption, DRIFT and XRD patterns. Gas-phase competitive dehydration/dehydrogenation reaction of cyclohexanol was carried out as a probe reaction and cyclohexene was usually the main reaction product, but different amounts of 1- and 3-methylcyclopentenes as well as cyclohexanone were always obtained. These results were compared to those obtained with 17 commercial inorganic solids (several metal oxides, sulfates and phosphates). A main unexpected conclusion was that cyclohexanol dehydration is obtained not only in acid sites but also in basic sites. (C) 2002 Elsevier Science B.V. All rights reserved.

引用

页码：93 / 107

页数：15

共 18 条

[1] Influence of the acid/base and redox properties of catalysts in the gas-phase dehydration-dehydrogenation of cyclohexanol on iron and titania containing mesoporous materials
Szegedi, Agnes
Popova, Margarita
Lazar, Karoly
REACTION KINETICS MECHANISMS AND CATALYSIS, 2011, 104 (02) : 291 - 301
[2] Influence of the acid/base and redox properties of catalysts in the gas-phase dehydration–dehydrogenation of cyclohexanol on iron and titania containing mesoporous materials
Ágnes Szegedi
Margarita Popova
Károly Lázár
Reaction Kinetics, Mechanisms and Catalysis, 2011, 104 : 291 - 301
[3] Comparison of gas-phase dehydration of propane polyols over solid acid-base catalysts
Tao, Li-Zhi
Chai, Song-Hai
Wang, Hao-Peng
Yan, Bo
Liang, Yu
Xu, Bo-Qing
CATALYSIS TODAY, 2014, 234 : 237 - 244
[4] Performance of solid acid-base catalysts for production of acrolein by gas-phase dehydration of aqueous glycerol
Xu, Bo-Qing
ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 2014, 248
[5] Sustainable production of acrolein: investigation of solid acid-base catalysts for gas-phase dehydration of glycerol
Chai, Song-Hai
Wang, Hao-Peng
Liang, Yu
Xu, Bo-Qing
GREEN CHEMISTRY, 2007, 9 (10) : 1130 - 1136
[6] Influence of surface acid-base properties of zirconia and titania based catalysts on the product selectivity in gas phase dehydration of glycerol
Stosic, Dusan
Bennici, Simona
Couturier, Jean-Luc
Dubois, Jean-Luc
Auroux, Aline
CATALYSIS COMMUNICATIONS, 2012, 17 : 23 - 28
[7] Influence of acid-base properties of the support on the catalytic performances of Pt-based catalysts in a gas-phase hydrogenation of acetonitrile
Saad, F.
Comparot, J. D.
Brahmi, R.
Bensitel, M.
Pirault-Roy, L.
APPLIED CATALYSIS A-GENERAL, 2017, 544 : 1 - 9
[8] Examination of acid-base properties of solid catalysts for gas phase dehydration of glycerol: FTIR and adsorption microcalorimetry studies
Stosic, Dusan
Bennici, Simona
Sirotin, Sergey
Stelmachowski, Pawel
Couturier, Jean-Luc
Dubois, Jean-Luc
Travert, Arnaud
Auroux, Aline K.
CATALYSIS TODAY, 2014, 226 : 167 - 175
[9] Influence of the acid-base/redox properties of TiOx-sepiolite supported vanadium oxide catalysts in the gas-phase selective oxidation of toluene
Bautista, FM
Campelo, JM
Luna, D
Luque, J
Marinas, JM
CATALYSIS TODAY, 2006, 112 (1-4) : 28 - 32
[10] Gas-phase synthesis, structure and surface acid-base properties of highly dispersed vanadia/titania/silica catalysts
Keränen, J
Guimon, C
Auroux, A
Iiskola, EI
Niinistö, L
PHYSICAL CHEMISTRY CHEMICAL PHYSICS, 2003, 5 (23) : 5333 - 5342

← 1 2 →