Synthesis and, photophysical properties for fluorescent hexameric metallomacrocycles: Zinc(II)-mediated self-assembly of bis(terpyridine) ligands

被引：28
|
作者：
Hwang, Seok-Ho
Moorefield, Charles N.
Wang, Pingshan
Kim, Jeong-Yeol
Lee, Sana-Won
Newkome, Georae R. [1 ]
机构：
[1] Univ Akron, Dept Polymer Sci, Akron, OH 44325 USA
[2] Univ Akron, Dept Chem, Akron, OH 44325 USA
[3] Univ Akron, Maurice Morton Inst Polymer Sci, Akron, OH 44325 USA
[4] SoongSil Univ, Dept Chem & Environm Engn, Seoul 156743, South Korea
来源：
INORGANICA CHIMICA ACTA | 2007年 / 360卷 / 05期
基金：
美国国家科学基金会;
关键词：
terpyridine; zinc complex; metallomacrocycle; self-assembly;
D O I：
10.1016/j.ica.2006.09.012
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
Two types of hexameric metallomacrocycles, [Zn-6(1)(6)(PF6)(12)] and [Zn-6(2)(6)(PF6)(12)], where 1 is 1,3-bis(2,2':6,2 ''-terpyridine)-5-tert-butylbenzene and 2 is 1,3-bis(2,2':6',2 ''-terpyridinylethynyl)-5-tert-butylbenzene, were self-assembled by capitalizing on terpyridine-Zn(II)-terpyridine connectivity. Their structural compositions were established by H-1 and C-13 NMR, UV-Vis, and mass spectrometry. Incorporation of an ethynyl group in the metallomacrocycle can play a role as an electron trapping site to enhance the molar extinction coefficiency and photocurrent generation. (c) 2006 Published by Elsevier B.V.
引用
收藏
页码：1780 / 1784
页数：5
相关论文
共 50 条
  • [1] Self-Assembly of π-Conjugated Bis(terpyridine) Ligands with Zinc(II) Ions: New Metallosupramolecular Materials for Optoelectronic Applications
    Winter, Andreas
    Friebe, Christian
    Chiper, Manuela
    Hager, Martin D.
    Schubert, Ulrich S.
    JOURNAL OF POLYMER SCIENCE PART A-POLYMER CHEMISTRY, 2009, 47 (16) : 4083 - 4098
  • [2] Self-assembly of [2+2] Co(II) metallomacrocycles and Ni(II) metallogels with novel bis(pyridylimine) ligands
    Kelly, Norman
    Gloe, Kerstin
    Doert, Thomas
    Hennersdorf, Felix
    Heine, Axel
    Maerz, Juliane
    Schwarzenbolz, Uwe
    Weigand, Jan J.
    Gloe, Karsten
    JOURNAL OF ORGANOMETALLIC CHEMISTRY, 2016, 821 : 182 - 191
  • [3] Self-assembly of tetra- and hexameric metallomacrocycles with Cd(II), Zn(II) and Fe(II) using a tristerpyridine ligand
    Wang, Lei
    ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 2018, 256
  • [4] Perylene-Based Bis-, Tetrakis-, and Hexakis(terpyridine) Ligands and Their Ruthenium(II)-Bis(terpyridine) Complexes: Synthesis and Photophysical Properties
    El-Batal, Hany
    Guo, Kai
    Li, Xiaopeng
    Wesdemiotis, Chrys
    Moorefield, Charles N.
    Newkome, George R.
    EUROPEAN JOURNAL OF ORGANIC CHEMISTRY, 2013, 2013 (18) : 3640 - 3644
  • [5] Photophysical Properties of Luminescent Zinc(II)Pyridinyloxadiazole Complexes and their Glassy Self-Assembly Networks
    Panunzi, Barbara
    Concilio, Simona
    Diana, Rosita
    Shikler, Rafi
    Nabha, Shiran
    Piotto, Stefano
    Sessa, Lucia
    Tuzi, Angela
    Caruso, Ugo
    EUROPEAN JOURNAL OF INORGANIC CHEMISTRY, 2018, (23) : 2709 - 2716
  • [6] Self-Assembly of Tetrameric and Hexameric Terpyridine-Based Macrocycles Using Cd(II), Zn(II), and Fe(II)
    Wang, Lei
    Zhang, Zhe
    Jiang, Xin
    Irvin, Jennifer A.
    Liu, Changlin
    Wang, Ming
    Li, Xiaopeng
    INORGANIC CHEMISTRY, 2018, 57 (07) : 3548 - 3558
  • [7] Self-Assembly, Disassembly, and Reassembly of Gold Nanorods Mediated by Bis(terpyridine)-Metal Connectivity
    Chan, Yi-Tsu
    Li, Sinan
    Moorefield, Charles N.
    Wang, Pingshan
    Shreiner, Carol D.
    Newkome, George R.
    CHEMISTRY-A EUROPEAN JOURNAL, 2010, 16 (14) : 4164 - 4168
  • [8] Dendron-Functionalized Bis(terpyridine)-Iron(II) or -Cadmium(II) Metallomacrocycles: Synthesis, Traveling-Wave Ion-Mobility Mass Spectrometry, and Photophysical Properties
    Wang, Jin-Liang
    Li, Xiaopeng
    Lu, Xiaocun
    Chan, Yi-Tsu
    Moorefield, Charles N.
    Wesdemiotis, Chrys
    Newkome, George R.
    CHEMISTRY-A EUROPEAN JOURNAL, 2011, 17 (17) : 4830 - 4838
  • [9] Synthesis and Self-Assembly of Dihydroxyperylene Bisimides for the Tuning of Photophysical Properties
    Li, Yongjun
    Qing, Zhihong
    Yu, Yanwen
    Liu, Taifeng
    Jiang, Runsheng
    Li, Yuliang
    CHEMISTRY-AN ASIAN JOURNAL, 2012, 7 (08) : 1934 - 1939
  • [10] Selective self-assembly of hexameric homo- and heteropolymetallic lanthanide wheels:: Synthesis, structure, and photophysical studies
    Chen, Xiao-Yan
    Bretonniere, Yann
    Pecaut, Jacques
    Imbert, Daniel
    Buenzli, Jean-Claude
    Mazzanti, Marinella
    INORGANIC CHEMISTRY, 2007, 46 (03) : 625 - 637
12345