Revision of the low-temperature structures of rhombohedral ZrCr2Dx (x∼3.8), and monoclinic ZrV2Dx (1.1<x<2.3) and HfV2Dx (x∼1.9)

被引：25

作者：

Kohlmann, H ^{[1
]}

Yvon, K ^{[1
]}

机构：

[1] Lab Cristallog, CH-1211 Geneva 4, Switzerland

来源：

JOURNAL OF ALLOYS AND COMPOUNDS | 2000年 / 309卷 / 1-2期

关键词：

metal hydrides; symmetry revision; crystal structure determination;

D O I：

10.1016/S0925-8388(00)01040-9

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The low temperature structures reported for the rhombohedral C14 type derivative ZrCr2D3.8, [Irodova & Suard, J. Alloys Comp. 299 (2000) 32-38] and the monoclinic C15 type derivatives ZrV2Dx (x=2.18, 1.94, 1.48, 1.18) and HfV2D1.92 [Irodova & Suard, J. Alloys Comp. 291 (1999) 184-189] are found to be centrosymmetric rather than non-centrosymmetric. New structure refinements based on the original neutron diffraction data collected at 100 K yield more consistent results and significantly different deuterium atom distributions. (C) 2000 Elsevier Science S.A. All rights reserved.

引用

页码：123 / 126

页数：4

共 3 条

[1] Neutron diffraction study of phase transitions in highly concentrated hydrogen solid solutions ZrV2Dx (4 < x < 5)
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PHYSICS OF THE SOLID STATE, 2006, 48 (07) : 1351 - 1355
[2] Low-temperature synthesis of LixMn0.67Ni0.33O2 (0.2<x<0.33) nanowires with a hexagonal layered structure
Park, DH
Lim, ST
Hwang, SJ
Yoon, CS
Sun, YK
Choy, JH
ADVANCED MATERIALS, 2005, 17 (23) : 2834 - +
[3] Evaluation of low-temperature specific heats and thermal conductivities of REGa2 (RE = Pr, Nd, Gd, Tb, Dy, Ho and Er) and Dy1-xHoxGa2 (0<x<1) intermetallic compounds as regenerator materials
Yagi, W
Iwata, H
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JAPANESE JOURNAL OF APPLIED PHYSICS PART 1-REGULAR PAPERS SHORT NOTES & REVIEW PAPERS, 1998, 37 (9A): : 4787 - 4791

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Revision of the low-temperature structures of rhombohedral ZrCr2Dx (x∼3.8), and monoclinic ZrV2Dx (1.1&lt;x&lt;2.3) and HfV2Dx (x∼1.9)

Revision of the low-temperature structures of rhombohedral ZrCr2Dx (x∼3.8), and monoclinic ZrV2Dx (1.1<x<2.3) and HfV2Dx (x∼1.9)