Magnetic studies of nickel hydride nanoparticles embedded in chitosan matrix

In this work we present a method to produce NiH (beta-NiH phase) nanoparticles from Ni-Cu solid solution. The reduction of Ni2+ and Cu2+ occurred at high temperatures and in presence of glutaraldehyde, citric acid and chitosan biopolymer. The samples are mainly composed of Ni and NiH phases with particles sizes ranging from 9 to 27 nm. DC magnetization studies reveal the presence of hydrogen-poor nickel hydride phase (alpha-NiH phase) which enhances the saturation magnetization at temperatures below 50 K. Stability of samples stored in air after 8 months was verified, and thermal treatment at 350 degrees C in presence of air transformed the samples to Ni and Cu oxides. Furthermore, we present a discussion regarding the mechanism of Ni2+ and Cu2+ chemical reduction. (C) 2017 Elsevier B.V. All rights reserved.